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Journal of Polymer Research

, Volume 14, Issue 1, pp 61–66 | Cite as

Thermal and Mechanical Properties of Poly(arylene ether ketone)s having Pendant Tertiary Butyl Groups

  • Emel Yıldız
  • Tülay Yılmaz İnan
  • Hüseyin Yıldırım
  • Abdülkadir Kuyulu
  • Atilla Güngör
Article

Abstract

An aromatic bisphenol which contains bulky tertiary butyl group, 5-tert-butyl-1,3-bis(4-hydroxybenzoyl)benzene (2) was synthesized in high yield and purity by the reaction of 5-tert-butyl-1,3-bis(4-fluorobenzoyl)benzene with KOH solution in presence of DMSO. It was polymerized with activated bisarylhalides via aromatic nucleophilic substitution reaction to prepare a series of high molecular weight poly(arylene ether ketone)s (P1–P5), containing pendant tertiary butyl groups. The effect of molecular structure on the physical, thermal, mechanical and adhesion properties of the polymers were investigated.

Key words

high performance polymers mechanical properties polycondensation poly(arylene ether ketones) 

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References

  1. 1.
    B. Francis, V. L. Rao and R. Ramaswamy, Polym. Eng. Sci., 45, 1645 (2005).CrossRefGoogle Scholar
  2. 2.
    B. Francis, S. Thomas, A. Viswanathan, R. Ramaswamy, S. Jose and L. Rao, J. Polym. Sci., B, Polym. Phys., 44, 541–556 (2006).CrossRefGoogle Scholar
  3. 3.
    G. R. Belbin and P. A. Staniland, Philos. Trans. R. Soc. Lond., A, 322, 451 (1987).CrossRefGoogle Scholar
  4. 4.
    J. P. Critchely, G. J. Knight and W. W. Wright, Heat-Resistant Polymers, Plenum, New York, 1983.Google Scholar
  5. 5.
    R. N. Johnson, US Pat. 4, 108, 837 (1978).Google Scholar
  6. 6.
    P. M. Hergenrother, B. J. Jensen and S. J. Havens, Polymer, 29, 358 (1988).CrossRefGoogle Scholar
  7. 7.
    E. Yıldız, T. Y. İnan, A. Güngör, H. Yıldırım and A. Kuyulu, Macromol. Mater. Eng., 286, 634–639 (2001).CrossRefGoogle Scholar
  8. 8.
    V. Percec, M. Grigoras, R. S. Clough and J. Fanjul, J. Polym. Sci., A, Polym. Chem., 33, 331 (1995).CrossRefGoogle Scholar
  9. 9.
    V. Percec, R. S. Clough, P. L. Rinaldi and V. E. Litman, Macromolecules, 27, 1535 (1994).CrossRefGoogle Scholar
  10. 10.
    T. Y. İnan, E. Ekinci, E. Yıldız, A. Kuyulu and A. Güngör, Macromol. Chem. Phys., 202, 532–540 (2001).CrossRefGoogle Scholar
  11. 11.
    T. Y. İnan, E. Ekinci, E. Yıldız, A. Kuyulu and A. Güngör, Macromol. Chem. Phys., 202, 541–545 (2001).CrossRefGoogle Scholar
  12. 12.
    P. M. Hergenrother, B. J. Jensen and S. J. Havens, Polymer, 29, 358 (1988).CrossRefGoogle Scholar
  13. 13.
    F. Herhold and A. Schneller, Adv. Mater., 4, 143 (1992).CrossRefGoogle Scholar
  14. 14.
    P. Moulinie, R. Paroli and Y. W. Zhi, J. Polym. Sci., A, Polym. Chem., 33, 2741 (1995).CrossRefGoogle Scholar
  15. 15.
    F. Rodriguez, Principle of Polymer Systems, Tata McGraw-Hill, New Delhi, 1970.Google Scholar
  16. 16.
    A. Bhatnagar, R. S. Mani, B. King and D. K. Mohanty, Macromol. Chem. Phys., 197, 315, (1996).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Emel Yıldız
    • 1
  • Tülay Yılmaz İnan
    • 1
  • Hüseyin Yıldırım
    • 2
  • Abdülkadir Kuyulu
    • 2
  • Atilla Güngör
    • 3
  1. 1.Chemistry and Environment InstituteTÜBİTAK Marmara Research CenterGebze-KocaeliTurkey
  2. 2.Department of ChemistryYıldız Technical UniversityŞişli İstanbulTurkey
  3. 3.Faculty of Art & Science, Department of ChemistryMarmara UniversityGöztepe-İstanbulTurkey

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