A mathematical model of a unimolecular heterogeneous catalytic reaction is considered in the case where the adsorbate can diffuse along the surface of a catalyst and the desorption of the reaction product from the surface of the adsorbent is instantaneous. The model is described by a coupled parabolic system. The existence and uniqueness of a classical solution are established. Bibliography: 16 titles.
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References
I. Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc. 40, 1361–1403 (1918).
A. Ambrazevičius, “Solvability of a coupled system of parabolic and ordinary differential equations,” Centr. Eur. J. Math. 8, No. 3, 537–547 (2010).
A. Ambrazevičius, “Existence and uniqueness theorem to a unimolecular heterogeneous catalytic reaction model,” Nonlinear Anal., Model. Control 15, No. 4, 405-421 (2010).
J. Kankare and I. A. Vinokurov, “Kinetics Langmuirian adsorption onto planar, spherical, and cylindrical surfaces,” Langmuir, 15, 5591–5599 (1999).
V. Skakauskas and P. Katauskis, “Numerical solving of coupled systems of parabolic and ordinary differential equations,” Nonlinear Anal., Model. Control 15, No. 3, 351-360 (2010).
V. Skakauskas and P. Katauskis, “Numerical study of the kinetics of unimolecular heterogeneous reactions onto planar surfaces,” J. Math. Chem. [In press]
B. Goldstein and M. Dembo, “Approximating the effects of diffusion on reversible reactions at the cell surface: Ligand-Receptor kinetics,” Biophys. J. 68 1222-1230 (1995).
V. Skakauskas, P. Katauskis, and A. Skvortsov, “A reaction-diffusion model of the receptortoxin-antibody interaction,” Theor. Biol. Med. Model. [in press]
V. Skakauskas and P Katauskis, “On the kinetics of the Langmuior-type heterogeneous reactions,” Nonlinear Anal., Model. Control [Submitted]
H. Levine and W. J. Rappel, “Membrane-bound Turing patterns,” Phys. Rev. E 72, No. 6, 061912 (2005).
C. V. Pao, Nonlinear Parabolic and Elliptic Equations, Plenum Press, New York (1992).
S. G. Mikhlin, Linear Partial Differential Equations [In Russian], Vyssh. Shkol., Moscow (1977).
D. K. Faddeev, B. Z. Vulikh, and N. N. Uraltseva, Selected Chapters of Analysis and Higher Algebra, [in Russian], Leningr. Univ. Press, Leningr. (1981).
A. Friedman, Partial Differential Equations of Parabolic Type Prentice-Hall, Englewood Cliffs, N.J. (1964).
O. A. Ladyzhenskaya, V. A. Solonnikov, and N. N. Uraltseva, Linear and Quasilinear Equation of Parabolic Type, Am. Math. Soc., Providence, RI (1968).
W. Pogorzelski, “Propriétés des intégrales de l‘équation parabolique normale” [in French], Ann. Pol. Math. 4, 61–92 (1957).
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Translated from Problems in Mathematical Analysis 65, May, 2012, pp. 13-26.
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Ambrazevičius, A. Solvability theorem for a model of a unimolecular heterogeneous reaction with adsorbate diffusion. J Math Sci 184, 383–398 (2012). https://doi.org/10.1007/s10958-012-0874-4
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DOI: https://doi.org/10.1007/s10958-012-0874-4