Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers

Journal of Solution Chemistry volume 50, pages290–298(2021)Cite this article

Abstract

In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-crown-4 and 15-crown-5 were measured at 298.15 K. The solvation and hydrogen bonding enthalpies of chloroform in the ethers were calculated. It was found that the hydrogen bonding enthalpies of chloroform in the ethers are significantly higher for linear than for cyclic ethers. The hydrogen bonding of ethers with chloroform was discussed in cases when ethers act as a solute or solvent.

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Acknowledgements

The reported study was funded by RFBR, project number 19-33-60096.

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Affiliations

  1. Institute of Chemistry, Saint Petersburg State University, Universitetskii Prospect 26, Saint Petersburg, 198504, Russia

    Ilnaz T. Rakipov & Konstantin N. Semenov

  2. Pavlov First Saint Petersburg State Medical University, L’va Tolstogo Ulitsa 6–8, Saint Petersburg, 197022, Russia

    Konstantin N. Semenov

  3. Department of Physical Chemistry, Kazan Federal University, Kremlevskaya 18, Kazan, 420008, Russia

    Artem A. Petrov, Aydar A. Akhmadiyarov, Artashes A. Khachatrian, Aliya R. Fakhurtdinova & Boris N. Solomonov

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  1. Ilnaz T. Rakipov
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  2. Konstantin N. Semenov
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Correspondence to Ilnaz T. Rakipov.

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Rakipov, I.T., Semenov, K.N., Petrov, A.A. et al. Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers. J Solution Chem 50, 290–298 (2021). https://doi.org/10.1007/s10953-021-01059-6

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Keywords

  • Solution enthalpies
  • Linear and cyclic ethers
  • Proton donors
  • Intermolecular interaction
  • Solution calorimetry