Journal of Solution Chemistry

, Volume 47, Issue 3, pp 498–510 | Cite as

Liquid–Liquid Equilibrium of Water + 1-Propanol or 1-Butanol + Dibutyl Ether Ternary Systems: Measurements and Correlation at Three Temperatures

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Abstract

Liquid–liquid equilibrium (LLE) date for the ternary systems of {water + 1-propanol + dibutyl ether (DBE)} and (water + 1-butanol + DBE) were determined at T = (293.15, 303.15, 308.15) K under atmospheric pressure. Distribution coefficients and separation factors of 1-propanol in the mixtures were calculated and are discussed. The influence of temperature on the liquid phase regions was analyzed. In addition, the experimental values were correlated well with the modified and extended UNIQUAC models; the modified UNIQUAC model represents the data better than the extended UNIQUAC model.

Keywords

Liquid–liquid equilibrium Dibutyl ether Modified UNIQUAC model Extended UNIQUAC model 
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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of ChemistryJinan UniversityGuangzhouPeople’s Republic of China

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