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Journal of Solution Chemistry

, Volume 47, Issue 2, pp 336–352 | Cite as

Thermodynamic Properties of Ternary Ionic Liquid Mixture Containing a Common Ion: Excess Molar Volumes, Excess Isentropic Compressibilities, Excess Molar Enthalpies and Excess Heat Capacities

  • Heena Gupta
  • Sunita Malik
  • Vinod Kumar Sharma
Article

Abstract

In the present investigations, the excess molar volumes, \( V_{ijk}^{\text{E}} \), excess isentropic compressibilities, \( \left( {\kappa_{S}^{\text{E}} } \right)_{ijk} \), and excess heat capacities, \( \left( {C_{p}^{\text{E}} } \right)_{ijk} \), for ternary 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (i) + 1-butyl-3-methylimidazolium tetrafluoroborate (j) + 1-ethyl-3-methylimidazolium tetrafluoroborate (k) mixture at (293.15, 298.15, 303.15 and 308.15) K and excess molar enthalpies, \( \left( {H^{\text{E}} } \right)_{ijk} \), of the same mixture at 298.15 K have been determined over entire composition range of x i and x j . Satisfactorily corrections for the excess properties \( V_{ijk}^{\text{E}} \), \( \left( {\kappa_{S}^{\text{E}} } \right)_{ijk} \), \( \left( {H^{\text{E}} } \right)_{ijk} \) and \( \left( {C_{p}^{\text{E}} } \right)_{ijk} \) have been obtained by fitting with the Redlich–Kister equation, and ternary adjustable parameters along with standard errors have also been estimated. The \( V_{ijk}^{\text{E}} \), \( \left( {\kappa_{S}^{\text{E}} } \right)_{ijk} \), \( \left( {H^{\text{E}} } \right)_{ijk} \) and \( \left( {C_{p}^{\text{E}} } \right)_{ijk} \) data have been further analyzed in terms of Graph Theory that deals with the topology of the molecules. It has also been observed that Graph Theory describes well \( V_{ijk}^{\text{E}} \), \( \left( {\kappa_{S}^{\text{E}} } \right)_{ijk} \), \( \left( {H^{\text{E}} } \right)_{ijk} \) and \( \left( {C_{p}^{\text{E}} } \right)_{ijk} \) values of the ternary mixture comprised of ionic liquids.

Keywords

Densities Excess isentropic compressibilities Excess heat capacities Excess molar enthalpies Graph Theory 

Notes

Acknowledgements

The authors are thankful to Mr. K. Chandrasekhar Reddy, SSBN College, Anantapur, for providing the Gaussian-09 facility and C-DAC, PUNE, India for providing the computational work. V. K. Sharma is grateful to the University Grant Commission (UGC), New Delhi for the award of SAP.

Supplementary material

10953_2018_719_MOESM1_ESM.docx (163 kb)
Supplementary material 1 (DOCX 162 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Heena Gupta
    • 1
  • Sunita Malik
    • 1
  • Vinod Kumar Sharma
    • 1
  1. 1.Department of ChemistryM. D. UniversityRohtakIndia

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