Abstract
Surface properties of binary mixtures of 1,2-ethanediol, 1,2-propanediol and 1,4-butanediol with acetonitrile have been measured by the surface tension method at T = 298.15 K and atmospheric pressure. The surface tension has been predicted based on the Suarez method. This method combines a model for the description of surface tension of liquid mixtures by using the UNIFAC group contribution method for calculation of activity coefficients. Also, the results have been discussed in terms of surface concentration and lyophobicity using the extended Langmuir isotherm. The results provide information on the molecular interactions between the unlike molecules that exist at the surface and the bulk phase. Finally, experimental values of the surface tension have been correlated by the Redlich–Kister and Wang–Chen polynomial equations over the whole mole fraction range.
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Bezerram, E.S., Santos, J.M.T., Paredes, M.L.L.: A new predictive model for liquid/air surface tension of mixtures: hydrocarbon mixtures. Fluid Phase Equilib. 288, 55–62 (2010)
Villares, A., Giner, B., Artigas, H., Lafuente, C., Royo, F.M.: Study of the surface tensions of cyclohexane or methylcyclohexane with some cyclic ethers. J. Solution Chem. 34, 185–198 (2005)
Pandey, J.D., Srivastava, T.: Surface tension: a theoretical study of multicomponent solutions. J. Mol. Liq. 155, 51–56 (2010)
Maximino, R.B.: Surface tension and density of binary mixtures of monoalcohols, water and acetonitrile: equation of correlation of the surface tension. Phys. Chem. Liq. 47, 475–486 (2009)
Suarez, J.T., Torres-Marchal, C., Rasmussen, P.: Prediction of surface tensions of nonelectrolyte solutions. Chem. Eng. Sci. 44, 782–785 (1989)
Butler, J.A.V.: The thermodynamics of the surfaces of solutions. Proc. R. Soc. Lond. 135, 348–375 (1932)
Li, C., Wang, W., Zihao, W.: A surface tension model for liquid mixtures based on the Wilson equation. Fluid Phase Equilib. 175, 185–196 (2000)
Bahramian, A., Danesh, A.: Prediction of liquid–liquid interfacial tension in multi-component systems. Fluid Phase Equilib. 221, 197–205 (2004)
Kalies, G., Brauer, P., Schmidt, A., Messow, U.: Calculation and prediction of adsorption excesses on the ternary liquid mixture/air interface from surface tension measurements. J. Colloid Interface Sci. 247, 1–11 (2002)
Queimada, A.J., Rolo, L.I., Caco, A.I., Marrucho, I.M., Stenby, E.H., Coutinho, J.A.P.: Prediction of viscosities and surface tensions of fuels using a new corresponding states model. Fuel 85, 874–877 (2006)
Zuo, Y.X., Stenby, E.H.: Corresponding-states and parachor models for the calculation of interfacial tensions. Can. J. Chem. Eng. 75, 1130–1137 (1997)
Mejia, A., Segura, H., Vega, L.F., Wisniak, J.: Simultaneous prediction of interfacial tension and phase equilibria in binary mixtures: an approach based on cubic equations of state with improved mixing rules. Fluid Phase Equilib. 227, 225–238 (2005)
Toxvaerd, S.: Surface structure of a square-well. Fluid J. Chem. Phys. 57, 4092–4098 (1972)
Tjahjono, M., Garland, M.: A new modified parachor model for predicting surface compositions of binary liquid mixtures. On the importance of surface volume representation. J. Colloid Interface Sci. 345, 528–537 (2010)
Sprow, F.B., Prausnitz, J.M.: Surface thermodynamics of liquid mixtures. Can. J. Chem. Eng. 45, 25–28 (1967)
Nath, S.J.: Surface tension of nonideal binary liquid mixtures as a function of composition. J. Colloid Interface Sci. 209, 116–122 (1999)
Rafati, A.A., Ghasemian, E.: Experimental and theoretical study of surface tension of binary mixtures of (n-alkyl acetates + heptane, benzene, and toluene). J. Chem. Thermodyn. 41, 386–391 (2009)
Giner, B., Cea, P., Lopez, M.C., Royo, F.M., Lafuente, C.: Surface tensions for isomeric chlorobutanes with isomeric butanols. J. Colloid Interface Sci. 275, 284–289 (2004)
Sprow, F.B., Prausnitz, J.: Surface tensions of simple liquid mixtures. Trans. Faraday Soc. 62, 1105–1111 (1966)
Tester, J.W., Modell, M.: Thermodynamics and Its Applications, 3rd edn. Prentice Hall, New York (1997)
Gmehling, J., Rasmussen, P., Fredenslund, A.: Vapor–liquid equilibriums by UNIFAC group contribution. Revision and extension. 2. Ind. Eng. Chem. Process Des. Dev. 21, 118–127 (1982)
Larsen, B.L., Rasmussen, P., Fredenslund, A.: A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing. Ind. Eng. Chem. Res. 26, 2274–2286 (1987)
Chattoraj, D.K., Birdi, K.S.: Adsorption and the Gibbs Surface Excess. Plenum Press, New York (1984)
Gmehling, J., Li, J., Schiler, M.: A modified UNIFAC model. 2. Present parameter matrix and results for different thermodynamic properties. Ind. Eng. Chem. Res. 32, 178–193 (1993)
Rafati, A.A., Ghasemian, E.: Study of surface tension and surface properties of binary alcohol/n-alkyl acetate mixtures. J. Colloid Interface Sci. 328, 385–390 (2008)
Pineiro, A., Brocos, P., Amigo, A., Fadrique, J.G., Lemus, M.G.: Extended Langmuir isotherm for binary liquid mixtures. Langmuir 17, 4261–4266 (2001)
Redlich, O.J., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)
Wohlfarth, C., Wohlfarth, B.: Surface Tension of Pure Liquids and Binary Liquid Mixtures, vol. 16. Springer, New York (1997)
Kinart, B., Kinart, C.M., Kolasinski, W.J., Cwiklinska, A.: Physicochemical properties of acetonitrile–butan-1-ol and acetonitrile–butan-2-ol mixtures. Phys. Chem. Liq. 38, 583–597 (2000)
Iloukhani, H., Almasi, M.: Densities, viscosities, excess molar volumes, and refractive indices of acetonitrile and 2-alkanols binary mixtures at different temperatures: experimental results and application of the Prigogine–Flory–Patterson theory. Thermochim. Acta 495, 139–148 (2009)
Cocchi, M., Marchetti, A., Pigani, L., Sanna, G., Tassi, L., Ulrici, A., Vaccari, G., Zanardi, C.: Density and volumetric properties of ethane-1,2-diol + di-ethylen-glycol mixtures at different temperatures. Fluid Phase Equilib. 172, 93–104 (2000)
Geyer, H., Ulbig, P., Gornert, M.: Measurement of densities and excess molar volumes for (1,2-ethanediol, or 1,2-propanediol, or 1,2-butanediol + water) at the temperatures (278.15, 288.15, 298.15, 308.15, and 318.15) K and for (2,3-butanediol + water) at the temperatures (308.15, 313.15, and 318.15) K. J. Chem. Thermodyn. 32, 1585–1596 (2000)
Wohlfarth, C., Wohlfarth, B.: Surface Tension of Pure Liquids and Binary Liquid Mixtures, vol. 24. Springer, New York (2008)
Compostizo, A., Pascual, A.D., Colin, A.C., Rubio, R.G.: Density–pressure relationship in hydrogen-bonded mixtures: 1,4-butanediol + 1-dodecanol. J. Chem. Eng. Data 50, 591–595 (2005)
Huh, C., Mason, S.G.: A rigorous theory of ring tensiometery. Colloid Polym. Sci. 253, 266–280 (1975)
Rafati, A.A., Ghasemian, E.: Surface tension and surface properties of binary mixtures of 1,4-dioxane or N, N-dimethyl formamide with n-alkyl acetates. J. Chem. Eng. Data 54, 3224–3228 (2009)
Constantinides, A.: Applied Numerical Methods with Personal Computers, 2nd edn. McGraw-Hill, Singapore (1997)
Paquette, L.J.: M.S. thesis. Laurentian University, Canada (1982)
Rafati, A.A., Bagheri, A., Khanchi, A.R., Ghasemian, E., Najafi, M.: Application of the UNIFAC model for prediction of surface tension and thickness of the surface layer in the binary mixtures. J. Colloid Interface Sci. 355, 252–258 (2011)
Poling, B.E., Prausnitz, J.M., O’Connell, J.P.: The Properties of Gases and Liquids, 5th edn. McGraw-Hill, New York (2004)
Bagheri, A., Amiri-Majed, A.H.: Surface thermodynamics of binary mixtures of aliphatic alcohols in heavy water. J. Chem. Thermodyn. 51, 45–50 (2012)
Torres, R.B., Francesconi, A.Z., Volpe, P.L.O.: Experimental study and modelling using the ERAS-model of the excess molar volume of acetonitrile–alkanol mixtures at different temperatures and atmospheric pressure. Fluid Phase Equilib. 210, 287–306 (2003)
Calvo, E., Pintos, M., Amigo, A., Bravo, R.: Surface tension and density of mixtures of 1,3-dioxolane + alkanols at 298.15 K: analysis under the extended Langmuir model. J. Colloid Interface Sci. 272, 438–443 (2004)
Rafati, A.A., Bagheri, A., Najafi, M.: Surface tension of non-ideal binary and ternary liquid mixtures at various temperatures and p = 81.5 kPa. J. Chem. Thermodyn. 43, 248–254 (2011)
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Bagheri, A., Rafati, A.A., Tajani, A.A. et al. Prediction of the Surface Tension, Surface Concentration and the Relative Gibbs Adsorption Isotherm of Non-ideal Binary Liquid Mixtures. J Solution Chem 42, 2071–2086 (2013). https://doi.org/10.1007/s10953-013-0093-8
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DOI: https://doi.org/10.1007/s10953-013-0093-8