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Journal of Solution Chemistry

, Volume 41, Issue 3, pp 392–409 | Cite as

Potentiometric Determination of the Stability Constants of Trimethyltin(IV) Chloride Complexes with Imino-bis(Methylphosphonic Acid) in Water and Dioxane–Water Mixtures

  • Ahmed A. El-Sherif
Article

Abstract

The interaction of trimethyltin(IV) (TMT) with imino-bis(methylphosphonic acid) (IDP), abbreviated as H4L, was investigated at 25 °C and at ionic strength 0.1 mol⋅dm−3 (NaNO3) using a potentiometric technique. The formation constants of the complexes formed in solution were calculated using the nonlinear least-squares program MINIQUAD-75. The stoichiometry and stability constants are reported for the complexes formed. The results show the formation of 110, 111, 112 and 11-1 complexes for the TMT–IDP system. The concentration distribution of the various complex species was evaluated. The effect of dioxane as a solvent, on both the protonation constants and the formation constants of trimethyltin(IV) complexes with IDP, is discussed. The thermodynamic parameters ΔH and ΔS calculated from the temperature dependence of the equilibrium constants were evaluated. The effect of ionic strength on the protonation constants of IDP is also discussed.

Keywords

Trimethyltin(IV) Imino-bis(methylphosphonic acid) Stability constants Speciation Equilibria Ionic strength Thermodynamic parameters 

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceCairo UniversityCairoEgypt

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