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Journal of Solution Chemistry

, Volume 40, Issue 10, pp 1769–1783 | Cite as

Thermodynamic Study of Ternary Mixtures Containing 1-Methyl Pyrrolidin-2-one, Propan-2-ol and Benzene or Methyl Benzene or Cyclohexane

  • Yameeka Chhikara
  • J. S. Yadav
  • Dimple Sharma
  • V. K. Sharma
Article

Abstract

Densities, ρ 123, and speeds of sound, u 123, of 1-methyl pyrrolidin-2-one (1) + benzene or methyl benzene or cyclohexane (2) + propan-2-ol (3) ternary mixtures have been measured over the entire composition range at 308.15 K and atmospheric pressure. The resulting ρ 123 and \(V_{123}^{\mathrm{E}}\) data were utilized to predict excess isentropic compressibilities, \((\kappa_{S}^{\mathrm{E}})_{123}\), of the studied (1+2+3) mixtures. The observed \(V_{123}^{\mathrm{E}}\) and \((\kappa_{S}^{\mathrm{E}})_{123}\) data have been analyzed in terms of Graph theory (which involved the topology of a molecule). It has been observed that \(V_{123}^{\mathrm{E}}\) and \((\kappa_{S}^{\mathrm{E}})_{123}\) values determined by Graph theory compare well with their corresponding experimental values.

Keywords

Connectivity parameter of third degree, 3ξ Excess molar volumes, \(V_{123}^{\mathrm{E}}\) Excess isentropic compressibilities, \((\kappa_{S}^{\mathrm{E}})_{123}\) Speeds of sound, u123 

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Yameeka Chhikara
    • 1
  • J. S. Yadav
    • 2
  • Dimple Sharma
    • 3
  • V. K. Sharma
    • 1
  1. 1.Department of ChemistryMaharshi Dayanand UniversityRohtakIndia
  2. 2.Department of ChemistryA.I.J.H.M. CollegeRohtakIndia
  3. 3.P.D.M. College of Engineering for WomenBahadurgarhIndia

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