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Journal of Solution Chemistry

, Volume 40, Issue 6, pp 980–988 | Cite as

Dissociation Constant of Acetic Acid in (N,N-Dimethylformamide + Water) Mixtures at the Temperature 298.15 K

  • Yuliya A. Fadeeva
  • Lyubov P. Safonova
Article

Abstract

In the present work the thermodynamic dissociation constants of acetic acid were determined in (N,N-dimethylformamide (DMF) + water) mixtures over the DMF mole fraction range from 0 to 0.65 at the temperature 298.15 K by the potentiometric titration method. The dissociation constant in pure DMF was obtained by extrapolation and comparative calculation methods. The dependence of the acetic acid dissociation constant on the mixed solvent composition was fitted with linear multiple regression of the solvatochromic parameters of (DMF + water) mixtures at every studied composition.

Keywords

Dissociation constant Acetic acid N,N-Dimethylformamide Potentiometric titration 

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© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Institute of Solution Chemistry of the Russian Academy of SciencesIvanovoRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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