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Journal of Solution Chemistry

, Volume 40, Issue 3, pp 415–429 | Cite as

Densities, Viscosities, Speeds of Sound, FT-IR and 1H-NMR Studies of Binary Mixtures of n-Butyl Acetate with Ethanol, Propan-1-ol, Butan-1-ol and Pentan-1-ol at 298.15, 303.15, 308.15 and 313.15 K

  • Mehdi Hasan
  • Apoorva P. Hiray
  • Ujjan B. Kadam
  • Dinesh F. Shirude
  • Keshav J. Kurhe
  • Arun B. Sawant
Article

Abstract

Densities, viscosities and speeds of sound of binary mixtures of ethanol, propan-1-ol, butan-1-ol and pentane-1-ol with n-butyl acetate have been measured over the entire range of composition at temperatures of 298.15, 303.15, 308.15 and 313.15 K and atmospheric pressure. From the experimental densities, viscosities and speeds of sound, the excess molar volumes V E, deviations in viscosity Δη, and deviations in isentropic compressibility Δκ S have been calculated. The excess molar volumes and deviations in isentropic compressibility are positive for all the binary systems studied over the whole composition, while deviations in viscosities are negative for all of the binary mixtures. The excess molar volumes, deviations in viscosity, and deviations in isentropic compressibility have been fitted to a Redlich–Kister type polynomial equation. FTIR and 1H-NMR studies of these mixtures are also reported.

Keywords

Density Viscosity Speed of sound IR 1H-NMR n-Butyl acetate Alkanols 

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References

  1. 1.
    Nikam, P.S., Shirsat, L.N., Hasan, M.: Density and viscosity studies of binary mixtures of acetonitrile with methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, 2-methylpropan-1-ol, 2-methylpropan-2-ol at (298.15, 303.15, 308.15 and 313.15) K. J. Chem. Eng. Data 43, 732–737 (1998) CrossRefGoogle Scholar
  2. 2.
    Nikam, P.S., Jadhav, M.C., Hasan, M.: Volumetric, viscometric and ultrasonic behaviour of dimethylsulfoxide with normal alcohols (C1–C4) at 308.15 K. J. Mol. Liquids 76, 1–11 (1998) CrossRefGoogle Scholar
  3. 3.
    Nikam, P.S., Jadhav, M.C., Hasan, M.: Molecular interactions in mixtures of dimethylsulfoxide with some alkanols—an ultrasonic study. Acustica Acta Acoust. 83, 86–89 (1997) Google Scholar
  4. 4.
    Nikam, P.S., Mahale, T.R., Hasan, M.: Ultrasonic study of alkanols (C1–C4) in binary mixtures containing ethyl acetate as common component. Acustica Acta Acoust. 84, 579–584 (1998) Google Scholar
  5. 5.
    Nikam, P.S., Jagdale, B.S., Sawant, A.B., Hasan, M.: Ultrasonic study of binary liquid mixtures of benzonitrile with alkanols (C1–C3) at various temperatures. Acoust. Lett. 22, 199–203 (1999) Google Scholar
  6. 6.
    Kadam, U.B., Hiray, A.P., Sawant, A.B., Hasan, M.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of methanol with propan-1-ol and butan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 60–63 (2006) CrossRefGoogle Scholar
  7. 7.
    Hasan, M., Kadam, U.B., Hiray, A.P., Sawant, A.B.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of methanol with pentan-1-ol, hexan-1-ol and heptan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 671–675 (2006) CrossRefGoogle Scholar
  8. 8.
    Kadam, U.B., Hiray, A.P., Sawant, A.B., Hasan, M.: Densities, viscosities, and ultrasonic velocity studies of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol at T=(298.15 and 308.15) K. J. Chem. Thermodyn. 38, 1675–1683 (2006) CrossRefGoogle Scholar
  9. 9.
    Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and ultrasonic velocities of binary mixtures of methylbenzene with hexan-2-ol, heptan-2-ol and octan-2-ol at T=(298.15 and 308.15) K. Fluid Phase Equilib. 252, 89–95 (2007) CrossRefGoogle Scholar
  10. 10.
    Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and speed of sound studies of binary mixtures of methylbenzene with heptan-1-ol, octan-1-ol and decan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data 51, 1922–1926 (2006) CrossRefGoogle Scholar
  11. 11.
    Hasan, M., Shirude, D.F., Hiray, A.P., Kadam, U.B., Sawant, A.B.: Densities, viscosities and ultrasonic velocity studies of binary mixtures of toluene with heptan-1-ol, octan-1-ol and decan-1-ol at 298.15 and 308.15 K. J. Mol. Liquids 135, 32–37 (2007) CrossRefGoogle Scholar
  12. 12.
    Nikam, P.S., Hasan, M., Shewale, R.P., Sawant, A.B.: Limiting ionic partial molar volumes of Cs+, Na+, (C4H9)4N+, Cl, Br, I, \(\mathrm{BPh}_{4}^{ -}\) in aqueous acetone at 298.15 K. J. Solution Chem. 32, 987–995 (2003) CrossRefGoogle Scholar
  13. 13.
    Marsh, K.N.: Recommended Reference Materials for the Realisation of Physicochemical Properties. Blackwell Sci., Oxford (1987) Google Scholar
  14. 14.
    Redlich, O., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948) CrossRefGoogle Scholar
  15. 15.
    Iloukhani, H.Z., Nojini, B.: Volumetric and acoustic properties of butyl acetate with some alkan-1-ols (C1–C6) at 298.15 K. Phys. Chem. Liq. 43, 429–440 (2005) CrossRefGoogle Scholar
  16. 16.
    Kiyohara, O., Benson, G.C.: Ultrasonic speeds and isentropic compressibilities of n-alkanol + n-heptane mixtures at 298.15 K. J. Chem. Thermodyn. 11, 861–873 (1979) CrossRefGoogle Scholar
  17. 17.
    Rai, R.D., Shukla, R.K., Shukla, A.K., Pandey, J.D.: Ultrasonic speeds and isentropic compressibilities of ternary liquid mixtures at (298.15±0.01) K. J. Chem. Thermodyn. 21, 125–129 (1989) CrossRefGoogle Scholar
  18. 18.
    Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents, Physical Properties and Methods of Purification, Techniques of Chemistry, vol. II, 4th edn. Wiley–Interscience, New York (1986) Google Scholar
  19. 19.
    Aminabhavi, T.M., Phayde, H.T.S., Khinnavar, R.K., Bindu, G.: Densities, refractive indices, speeds of sound, and viscosities of diethylene glycol dimethyl ether + butyl acetate at 298.15, 303.15, 308.15, 313.15, and 318.15 K. J. Chem. Eng. Data 38, 542–545 (1993) CrossRefGoogle Scholar
  20. 20.
    Aminabhavi, T.M., Patil, V.B.: Density, viscosity, and speed of sound in binary mixtures of 1-chloronaphthalene with methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, and hexan-1-ol in the temperature range (298.15–308.15) K. J. Chem. Eng. Data 43, 504–508 (1998) CrossRefGoogle Scholar
  21. 21.
    Aminabhavi, T.M., Aralaguppi, M.I., Harogoppad, S.B., Balundgi, R.H.: Densities, viscosities, refractive indices, and speeds of sound for methyl acetoacetate + aliphatic alcohols (C1–C8). J. Chem. Eng. Data 38, 31–39 (1993) CrossRefGoogle Scholar
  22. 22.
    Aminabhavi, T.M., Banerjee, K.: Density, viscosity, refractive index, and speed of sound in binary mixtures of 2-chloroethanol with alkanols (C1–C6) at 298.15, 303.15, and 308.15 K. J. Chem. Eng. Data 43, 509–513 (1998) CrossRefGoogle Scholar
  23. 23.
    Sastry, N.V., Valand, M.K.: Viscosities and densities for heptane + 1-pentanol, + 1-hexanol, + 1-heptanol, + 1-octanol, + 1-decanol, and + 1-dodecanol at 298.15 K and 308.15 K. J. Chem. Eng. Data 41, 1426–1428 (1996) CrossRefGoogle Scholar
  24. 24.
    Sastry, N.V., Valand, M.K.: Densities, viscosities, and relative permittivities for pentane + 1-alcohols (C1 to C12) at 298.15 K. J. Chem. Eng. Data 43, 152–157 (1998) CrossRefGoogle Scholar
  25. 25.
    Tu, C.H., Lee, S.L., Peng, I.H.: Excess volumes and viscosities of binary mixtures of aliphatic alcohols (C1–C4) with nitromethane. J. Chem. Eng. Data 46, 151–155 (2001) CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Mehdi Hasan
    • 1
  • Apoorva P. Hiray
    • 1
  • Ujjan B. Kadam
    • 1
  • Dinesh F. Shirude
    • 2
  • Keshav J. Kurhe
    • 2
  • Arun B. Sawant
    • 1
  1. 1.P.G. Department of Physical ChemistryM.S.G. CollegePinIndia
  2. 2.Arts, Science and Commerce CollegeNampurIndia

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