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Journal of Solution Chemistry

, Volume 34, Issue 2, pp 233–243 | Cite as

Molecular Interactions in Propylene Carbonate + n-Alkanols at 25 C

  • D. S. Wankhede
  • N. N. Wankhede
  • M. K. Lande
  • B. R. Arbad
Article

Abstract

Densities and viscosities of the binary mixtures of propylene carbonate with methanol, ethanol, propanol, butanol, and hexanol, along with those of the pure liquids, were measured over the entire mole fraction range at 25 C. Using the experimental values of densities ρ and viscosities η, the excess molar volumes VE, viscosity deviations Δη, excess Gibbs energies of activation of viscous flow ΔGE, and Grunberg–Nissan interaction parameters d12 were calculated from the linear dependence of these parameters on the composition of the mixtures.

Keywords

Densities viscosities binary mixtures molecular interactions excess molar volumes viscosity deviations excess Gibbs energies of activation of viscous flow Grunberg–Nissan interaction parameter 

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Copyright information

© Springer Science + Business Media, Inc. 2005

Authors and Affiliations

  • D. S. Wankhede
    • 1
  • N. N. Wankhede
    • 1
  • M. K. Lande
    • 1
  • B. R. Arbad
    • 1
  1. 1.Department of ChemistryDr. Babasaheb Ambedkar Marathwada UniversityAurangabadIndia

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