Skip to main content
Log in

Vapor Pressures, Osmotic and Activity Coefficients of Electrolytes in Protic Solvents at Different Temperatures. 3. Lithium Bromide in 2-Propanol

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Precise vapor pressure data for LiBr solutions in 2-propanol are given for temperatures ranging from (298.15 to 348.15) K. The molality range was from (0.0743 to 1.4825) mol-kg−1. Osmotic coefficients were calculated by taking into account the second virial coefficient of 2-propanol. The parameters of the Archer extension of the Pitzer model, MSA-NRTL model, and chemical model of Barthel are evaluated. The parameters of the Archer extension of the Pitzer model were used to calculate the activity coefficients of LiBr in 2-propanol solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Nasirzadeh, R. Neueder, and W. Kunz, J. Chem. Thermodyn. 36, 511 (2004).

    Google Scholar 

  2. K. Nasirzadeh, N. Papaiconomou, R. Neueder, and W. Kunz, J. Solution Chem. 33, 227 (2004).

    Article  Google Scholar 

  3. K. Nasirzadeh, R. Neueder, and W. Kunz, J. Solution Chem. 33, 1429 (2004).

    Google Scholar 

  4. J. Barthel and G. Lauermann, J. Solution Chem. 15, 869 (1986).

    Google Scholar 

  5. J. Barthel, R. Neueder, H. Poepke, and H. Wittmann, J. Solution Chem. 27, 1055 (1998).

    Article  Google Scholar 

  6. M. T. Zafarani-Moattar and M. Aria, J. Solution Chem. 30, 351 (2001).

    Google Scholar 

  7. D. G. Archer, J. Phys. Chem. Ref. Data 20, 509 (1991).

    Google Scholar 

  8. D. G. Archer, J. Phys. Chem. Ref. Data 21, 793 (1992).

    Google Scholar 

  9. N. Papaiconomou, J.-P. Simonin, O. Bernard, and W. Kunz, Phys. Chem. Chem. Phys. 4, 4435 (2002).

    Article  Google Scholar 

  10. J. Barthel, H. Krienke, and W. Kunz, Physical Chemistry of Electrolyte Solutions (Steinkopff-Verlag, Darmstadt,/Springer, Berlin, 1998).

    Google Scholar 

  11. K. Nasirzadeh, D. Zimin, R. Neueder, and W. Kunz, J. Chem. Eng. Data 49, 607 (2004).

    Google Scholar 

  12. B. E. Poling, J. M. Prausnitz, and J. P. O’Connnell, The Properties of Gases and Liquids (McGraw-Hill, Boston, 2002).

    Google Scholar 

  13. J. Barthel, R. Neueder, and P. Schröder, Electrolyte Data Collection, Vol. XII, Part 1b, (DECHEMA, Frankfurt, Germany, 1994).

    Google Scholar 

  14. D. G. Archer and J. A. Rard, J. Chem. Eng. Data 43, 791 (1998).

    Google Scholar 

  15. L. Blum, Mol. Phys. 30, 1529 (1975).

    Google Scholar 

  16. H. Renon and J. M. Prausnitz, AIChE J. 14, 135 (1968).

    Google Scholar 

  17. C. C. Chen and L. B. Evans, AIChE J. 28, 4 (1982).

    Google Scholar 

  18. H. Krienke, J. Barthel, M. Holovko, I. Protsykevich, and Y. Kalyushnyi, J. Mol. Liq. 87, 191 (2000).

    Google Scholar 

  19. J. Barthel, H. Krienke, R. Neueder, and M. Holovko, Fluid Phase Equilib. 194–197, 107 (2002).

    Google Scholar 

  20. J. A. Rard, S. L. Clegg, and D. A. Palmer, J. Solution Chem. 29, 1 (2000).

    Article  Google Scholar 

  21. K. S. Pitzer and G. Mayorga, J. Solution Chem. 3, 539 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Karamat Nasirzadeh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nasirzadeh, K., Neueder, R. & Kunz, W. Vapor Pressures, Osmotic and Activity Coefficients of Electrolytes in Protic Solvents at Different Temperatures. 3. Lithium Bromide in 2-Propanol. J Solution Chem 34, 9–24 (2005). https://doi.org/10.1007/s10953-005-2024-9

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-005-2024-9

Keywords

Navigation