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Martensitic Transformation and Magnetic Properties of the CuAl, CuAlMn, and CuAlMnZn Alloys

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Abstract

In the present work, the effect of alloying elements on the phase transformation which are formed by cooling effect in CuAl, CuAlMn, and CuAlMnZn (wt%) alloys are investigated using scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM) characterization techniques. From SEM observations, the martensite formation with different morphologies is observed in these alloys. But the results of the scanning electron microscope investigations presented in this work have not formed the precipitates in the CuAl alloy with Mn or Zn additions. We found that magnetic saturation and coercivity values decreased with the addition of Mn and Zn elements to the CuAl alloy. The findings confirmed the variation in magnetic properties, which occurred in the result of adding different alloying elements.

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References

  1. Funakubo, H.: Shape Memory Alloys (Translated from Japanese by J. B. Kennedy). Gordon and Breach Science Publishers, New York (1987)

    Google Scholar 

  2. Sutou, Y., Omori, T., Kainuma, R., Ishida, K.: Ductile Cu-Al-Mn based shape memory alloys: general properties and applications. Mater. Sci. Technol. 24(8), 896–901 (2008)

    Article  Google Scholar 

  3. Miyazaki, S., Fu, Y.Q., Huang, W.M.: Thin Film Shape Memory Alloys: Fundamentals and Device Applications. Cambridge University Press, New York (2009)

    Book  Google Scholar 

  4. Canbay, C.A., Tataroglu, A., Dere, A., Al-Ghamdi, A., Yakuphanoglu, F.: A new shape memory alloy film/p-Si solar light four quadrant detector for solar tracking applications. J. Alloys Compd. 688, 762–768 (2016)

    Article  Google Scholar 

  5. Kciuk, M., Chwastek, K., Kluszczynski, K., Szczygłowski, J.: A study on hysteresis behaviour of SMA linear actuators based on unipolar sigmoid and hyperbolic tangent functions. Sensors Actuators A 243, 52–58 (2016)

    Article  Google Scholar 

  6. Fu, Y., Huang, W., Du, H., Huang, X., Tan, J., Gao, X.: Characterization of TiNi shape-memory alloy thin films for MEMS applications. Surf. Coat. Technol. 145, 107–112 (2001)

    Article  Google Scholar 

  7. Han, J.H., Yoon, J., Jee, K.K., Vlassak, J.J.: Thermoelastic strain in polycrystalline Fe-Pd shape memory alloy thin film. Thin Solid Films 546, 196–199 (2013)

    Article  ADS  Google Scholar 

  8. Ullakko, K., Huang, J.K., Kantner, C., O’Handley, R.C., Kokorin, V.V.: Large magnetic-field-induced strains in Ni2MnGa single crystals. Appl. Phys. Lett. 69, 1966–1968 (1996)

    Article  ADS  Google Scholar 

  9. Coll, R., Escoda, L., Saurina, J., Sacnhez-Llamazares, L., Hernando, B., Sunol, J.J.: Martensitic transformation in Mn–Ni–Sn Heusler alloys. J. Therm. Anal. Calorim. 99, 905–909 (2010)

    Article  Google Scholar 

  10. Jiles, D.: Introduction to Magnetism and Magnetic Materials, 2nd edn. Chapman and Hall, London & New York (1998)

    Google Scholar 

  11. Jiles, D.C.: Recent advances and future directions in magnetic materials. Acta Mater. 51, 5907–5939 (2003)

    Article  Google Scholar 

  12. Callister, W.D. Jr: Materials science and engineering introduction: an introduction, 7th edn. Wiley, New York (2007)

  13. Carvalho, T.M., Adorno, A.T., Santos C.M.A., Silva, R.A.G.: IX Congresso Brasileiro de Análise Térmica e Calorimetria 09 a 12 de novembro de 2014 – Serra Negra – SP – Brasil

  14. Kumar, P., Jain, A.K., Hussain, S., Pandey, A., Dasgupta, R.: Changes in the properties of Cu-Al-Mn shape memory alloy due to quaternary addition of different elements. Revistamateria 20(1), 284–292 (2015)

    Google Scholar 

  15. Mallik, U.S., Sampath, V.: Influence of quaternary alloying additions on transformation temperatures and shape memory properties of Cu-Al-Mn shape memory alloy. J. Alloys Comp. 469, 156– 163 (2009)

    Article  Google Scholar 

  16. Yang, S., Su, Y., Wang, C., Liu, X.: Microstructure and properties of Cu–Al–Fe high-temperature shape memory alloys. Mater. Sci. Eng. B 185, 67–73 (2014)

    Article  Google Scholar 

  17. Virtanen, P., Tiainen, T., Lepisto, T.: Precipitation at faceting grain boundaries of Cu-Ni-Sn alloys. Mat. Sci. Eng. A 251, 269 (1998)

    Article  Google Scholar 

  18. Sasmaz, M., Bayri, A., Aydoğdu, Y.: The magnetic behavior and physical characterization of Cu-Mn-Al ferromagnetic shape memory alloy. J. Supercond. Nov. Magn. 24(1-2), 757–762 (2011)

    Article  Google Scholar 

  19. Kouvel, J.S.: Exchange anisotropy in alloys of composition (Ni, Fe)3Mn. J. Phys. Chem. Solids. 16, 152–157 (1960)

    Article  ADS  Google Scholar 

  20. Cullity, B.D.: Introduction to Magnetic Materials, vol. 134. Addison-Wesley, Reading (1972)

    Google Scholar 

  21. Prado, M.O., Lovey, F.C., Civale, L.: Magnetic properties of Cu–Mn–Al alloys with shape memory effect. Acta Mater. 46, 137–147 (1998)

    Article  Google Scholar 

  22. Aldirmaz, E., Guler, M., Guler, E.: Investigation of magnetic properties of phase transformations in copper-based alloys. J. Supercond. Nov. Magn. 30(5), 1257–1261 (2017)

    Article  Google Scholar 

  23. Aldirmaz, E.: Investigation of the magnetic behavior and physical properties of Cu-25.50%Mn-3.72%Zn Alloy. J. Supercond. Nov. Magn. 30(11), 3161–3166 (2017)

    Article  Google Scholar 

  24. Likhachev, A.A., Ullakko, K.: Fifth European symposium on martensitic transformations and shape memory alloys. J. Phys. IV France 11, Pr8-293–Pr8-298 (2001)

    Article  Google Scholar 

  25. Murakami, Y., Shindo, D., Oikawa, K., Kainuma, R., Ishida, K.: Magnetic domain structures in Co-Ni-Al shape memory alloys studied by Lorentz microscopy and electron holography. Acta Mater. 50, 2173–2184 (2002)

    Article  Google Scholar 

  26. Kouvel, J.S.: The ferromagnetic-antiferromagnetic properties of copper-manganese and silver-manganese alloys. Phys. Chem. Solids 21, 57–70 (1961)

    Article  ADS  Google Scholar 

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Funding

The financial aid of the Amasya University project No. FMB-BAP 17-0250 is gratefully acknowledged.

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Correspondence to E. Aldirmaz or M. Guler.

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Emre Gerdan, Y., Aldirmaz, E., Guler, M. et al. Martensitic Transformation and Magnetic Properties of the CuAl, CuAlMn, and CuAlMnZn Alloys. J Supercond Nov Magn 31, 3919–3923 (2018). https://doi.org/10.1007/s10948-018-4658-z

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  • DOI: https://doi.org/10.1007/s10948-018-4658-z

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