Synthesis, Structural, Magnetic and Electrical Characterization of Poly(o-phenylenediamine)/CoFe2O4 Nanocomposites

  • Nagarajan Kannapiran
  • Athianna Muthusamy
  • Siddeswaran Anand
  • Rajan Jayaprakash
Original Paper
  • 40 Downloads

Abstract

CoFe2O4 nanoparticles were prepared by an auto-combustion method, and poly(o-phenylenediamine) (PoPD)/CoFe2O4 nanocomposites containing different ratios CoFe2O4 (10, 20 and 30%) were synthesized by an in situ chemical oxidative polymerization method. Dielectric constant and loss of PoPD/CoFe2O4 nanocomposites were varied based on the dopant concentration. The crystalline sizes of the CoFe2O4 nanoparticles and PoPD/CoFe2O4 nanocomposites were calculated using XRD pattern, and it is also confirmed nanoparticles embedded in the PoPD matrix. The hysteresis loops of CoFe2O4 and nanocomposites show a ferromagnetic behaviour, and saturation magnetization of PoPD/CoFe2O4 nanocomposites increases with an increase in concentration of CoFe2O4 nanoparticles. TEM micrograph of PoPD/CoFe2O4 nanocomposites demonstrated CoFe2O4 nanoparticles deposited on the surface of PoPD matrix.

Keywords

PoPD CoFe2O4 TEM Dielectric constant 

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Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • Nagarajan Kannapiran
    • 1
  • Athianna Muthusamy
    • 1
  • Siddeswaran Anand
    • 1
  • Rajan Jayaprakash
    • 2
  1. 1.PG and Research Department of ChemistrySri Ramakrishna Mission Vidyalaya College of Arts and ScienceCoimbatoreIndia
  2. 2.Department of PhysicsSri Ramakrishna Mission Vidyalaya College of Arts and ScienceCoimbatoreIndia

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