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Particularities of the Magnetic State of CuO Nanoparticles Produced by Low-Pressure Plasma Arc Discharge

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Abstract

Copper oxide nanoparticles were produced by direct plasmachemical synthesis in a plasma arc discharge of low pressure. The formation of CuO nanoparticles with an average size of 12 nm and narrow size distribution intervals was determined by using the x-ray diffraction analysis and TEM microscopy methods. It was defined by using a vibration magnetometer and a SQUID magnetometer, that the magnetic properties of CuO nanoparticles with such size were extremely different from the magnetic properties of bulk antiferromagnetic CuO. Structural defects caused the formation of a ferromagnetic state, remaining at least up to the room temperature. The temperature of corresponding antiferromagnetic ordering was significantly decreased (down to ∼ 100 K). Meanwhile, some of the copper surface spins showed a spin-glass behavior at low temperatures.

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Acknowledgments

The work was performed with a support of the grant of the Russian Science Foundation (project no. 16-19-10054)

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Authors and Affiliations

  1. Krasnoyarsk Scientific Center of the Siberian Branch, Russian Academy of Science, Krasnoyarsk, Russia

    A. A. Lepeshev, I. V. Karpov, A. V. Ushakov & M. I. Petrov

  2. Siberian Federal University, Krasnoyarsk, 660074, Russia

    A. A. Lepeshev, I. V. Karpov, A. V. Ushakov & D. A. Balaev

  3. L.V. Kirensky Institute of Physics, Krasnoyarsk, 660036, Russia

    D. A. Balaev, A. A. Krasikov, A. A. Dubrovskiy, D. A. Velikanov & M. I. Petrov

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  1. A. A. Lepeshev
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  2. I. V. Karpov
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  3. A. V. Ushakov
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  4. D. A. Balaev
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Correspondence to A. A. Lepeshev.

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Lepeshev, A.A., Karpov, I.V., Ushakov, A.V. et al. Particularities of the Magnetic State of CuO Nanoparticles Produced by Low-Pressure Plasma Arc Discharge. J Supercond Nov Magn 30, 931–936 (2017). https://doi.org/10.1007/s10948-016-3885-4

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  • DOI: https://doi.org/10.1007/s10948-016-3885-4

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