Abstract
Temperature-dependent X-ray absorption spectra of the hole-doped La2−x Sr x CuO4 and electron-doped Nd2−x Ce x CuO4−δ high-temperature superconductors were investigated above the Cu K absorption edge. We observed strong anharmonicity in the superconductive CuO2 plane. For x=0.15 it was shown that part of oxygen ions oscillate in a double-well potential and their vibrations are correlated with the local electron (hole) pair transfer. We suppose that at a low temperature the phase coherence of the local pair movement is determined by the peculiarities of the perovskite-like structure which includes the stiff CuO n (n=4,6) complexes combined by collective rotational and breathing modes.
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This work was partly supported by Russian Foundation for Basic Researches (Grant 12-02-12077-ofi_m).
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Menushenkov, A.P., Kuznetsov, A.V., Chernikov, R.V. et al. Low Temperature Anharmonicity and Superconductivity in Cuprates. J Supercond Nov Magn 27, 925–928 (2014). https://doi.org/10.1007/s10948-013-2411-1
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DOI: https://doi.org/10.1007/s10948-013-2411-1