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Journal of Superconductivity and Novel Magnetism

, Volume 26, Issue 2, pp 437–442 | Cite as

Three-Dimensional Network Polymeric Structure of (2-Amino-5 Ammoniopyridinium)[CuCl4]: Crystal Supramolecularity and Magnetic Properties

  • Sondra Walha
  • Houcine Naïli
  • Samia Yahyaoui
  • Basem Fares Ali
  • Mark M. Turnbull
  • Tahar Mhiri
  • Seik Weng Ng
Original Paper

Abstract

A single crystal structure determination of the complex (C5H9N3)CuCl4 [henceforth I] has been carried out. It crystallizes in the orthorhombic space group Cmca, with the cell parameters a=6.7053(5) Å, b=22.4171(19) Å, c=13.4173(9) Å, V=2016.8(3) Å3, and Z=8. In the complex, the anion is comprised of infinite zigzag chains of monochloro-bridged \(\mathrm{CuCl}_{4}^{2-}\) units ⋯–CuCl3μ–Cl–CuCl3μ–Cl–CuCl3–⋯ surrounded by the pyridinium-ammonium cations. The Cu ions are five-coordinate to chloride ions in a distorted square-pyramidal geometry with the zigzag chains formed by corner-sharing polyhedra. The Cu ion is located 0.151 Å above the basal plane. In the crystal, there are four intermolecular hydrogen bonding interactions, linking the CuCl chains to the cations to form a 2D-network. The resulting 2D-networks are further linked by aryl⋯aryl (ππ) interactions within the cationic chains leading to a 3D-network. Variable temperature magnetic susceptibility data were fit to a one-dimensional S=1/2 antiferromagnetic chain model yielding C=0.44(1) emu-K/mol-Oe and J=−37(1) K.

Keywords

Crystal structure Polymeric CuCl4 anion N–H⋯Cl–Cu interactions ππ interactions 1D-antiferromagnetic chain 

Notes

Acknowledgements

We are grateful to Dr. Thierry Roisnel (Centre de Diffractométrie X, Sciences Chimiques de Rennes, Université de Rennes I) for supplying the single-crystal X-ray diffraction data collection.

Supplementary material

10948_2012_1759_MOESM1_ESM.txt (11 kb)
CCDC 824443 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by e-mailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033. (TXT 11 kB)

References

  1. 1.
    Braga, D., Desiraju, G.R., Miller, J.S., Orpen, A.G., Price, S.L.: CrystEngComm 4, 500–509 (2002) CrossRefGoogle Scholar
  2. 2.
    Desiraju, G.R.: Angew. Chem., Int. Ed. Engl. 34, 2311–2327 (1995) CrossRefGoogle Scholar
  3. 3.
    Mitzi, D.B.: Prog. Inorg. Chem. 48, 1–12 (1999) Google Scholar
  4. 4.
    Reinoso, S., Vitoria, P., Lezama, L., Luque, A., Zorrilla, J.M.: Inorg. Chem. 42, 3709–3711 (2003) CrossRefGoogle Scholar
  5. 5.
    Shapiro, A., Landee, C.P., Turnbull, M.M., Jornet, J., Deumal, M., Novoa, J.J., Robb, M.A., Lewis, W.: J. Am. Chem. Soc. 129, 952–959 (2007) CrossRefGoogle Scholar
  6. 6.
    Li, L., Turnbull, M.M., Landee, C.P., Jornet, J., Deumal, M., Novoa, J.J., Wikaira, J.L.: Inorg. Chem. 46, 11254–11265 (2007) CrossRefGoogle Scholar
  7. 7.
    Parent, A.R., Landee, C.P., Turnbull, M.M.: Inorg. Chim. Acta 360, 1943–1953 (2007) CrossRefGoogle Scholar
  8. 8.
    Carlin, R.L.: Magnetochemistry. Springer, Berlin (1986) CrossRefGoogle Scholar
  9. 9.
    Marcotrigiano, G., Menabue, L., Pellacani, G.C.: J. Coord. Chem. 9, 141–146 (1979) CrossRefGoogle Scholar
  10. 10.
    Long, G.S., Wei, M., Willett, R.D.: Inorg. Chem. 36, 3102–3107 (1997) CrossRefGoogle Scholar
  11. 11.
    Snively, L.O., Tuthill, G.F., Drumheller, J.E.: Phys. Rev. B 24, 5349–5355 (1981) ADSCrossRefGoogle Scholar
  12. 12.
    Nikolov, G.S.: Inorg. Chem. 33, 1144–1152 (1994) CrossRefGoogle Scholar
  13. 13.
    Ohba, S., Fujita, T.: Acta Crystallogr. Sect. C 51, 1481–1483 (1995) CrossRefGoogle Scholar
  14. 14.
    Willett, R.D., Grigereit, T.E., Zhou, P., Drumheller, J.E.: Inorg. Chem. 31, 3859–3863 (1992) CrossRefGoogle Scholar
  15. 15.
    Luque, A., Sertucha, J., Castillo, O., Roman, P.J.: New J. Chem. 25, 1208–1214 (2001) CrossRefGoogle Scholar
  16. 16.
    Walha, S., Naili, H., Yahyaoui, S., Ali, B.F., Turnbull, M.M., Mhiri, T., Bataille, T.: Solid State Sci. 13, 204–208 (2011) ADSCrossRefGoogle Scholar
  17. 17.
    Nonius: Kappa CCD Program Software. Nonius BV, Delft (1998) Google Scholar
  18. 18.
    Otwinowski, Z., Minor, W., Carter, C.W., Sweet, R.M. (eds.): Methods in Enzymology, vol. 276, pp. 307–326. Academic Press, New York (1997) Google Scholar
  19. 19.
    Sheldrick, G.M.: SADABS Bruker AXS Inc. Madison, Wisconsin, USA (2002) Google Scholar
  20. 20.
    Sheldrick, G.M.: Acta Cryst. A 46, 467–473 (1990) CrossRefGoogle Scholar
  21. 21.
    Sheldrick, G.M.: Acta Cryst. A 64, 112–122 (2008) CrossRefGoogle Scholar
  22. 22.
    Bersuker, I.B. (ed.): The Jahn–Teller Effect. Cambridge University Press, Cambridge (2006) Google Scholar
  23. 23.
    Pearson, R.G.: Proc. Natl. Acad. Sci. USA 72, 2104–2106 (1975) ADSCrossRefGoogle Scholar
  24. 24.
    Reinen, D., Atanasov, M.: Chem. Phys. 136, 27–46 (1989) CrossRefGoogle Scholar
  25. 25.
    Brown, I.D.: J. Appl. Crystallogr. 29, 479–480 (1996) CrossRefGoogle Scholar
  26. 26.
    Bhattacharya, R., Ray, M.S., Dey, R., Righi, L., Bocelli, G., Ghosh, A.: Polyhedron 21, 2561–2565 (2002) CrossRefGoogle Scholar
  27. 27.
    Raithby, P.R., Shields, G.P., Allen, F.H., Motherwell, W.D.: Acta Crystallogr., B Struct. Crystallogr. Cryst. Chem. 56, 444–454 (2000) CrossRefGoogle Scholar
  28. 28.
    El Essawi, M.M.: Transit. Metal Chem. 22, 117–122 (1997) CrossRefGoogle Scholar
  29. 29.
    Battaglia, L.G., Corardi, A.B., Ianelli, S.: J. Crystallogr. Spectrosc. Res. 23, 411–415 (1993) CrossRefGoogle Scholar
  30. 30.
    Kanazawa, A., Ikeda, T., Nagase, Y.: Chem. Mater. 12, 3776–3782 (2000) CrossRefGoogle Scholar
  31. 31.
    Bonner, J.C., Fisher, M.E.: Phys. Rev. 135, A640–A658 (1964) ADSCrossRefGoogle Scholar
  32. 32.
    Battaglia, L.P., Corradi, A.B., Marcotrigiano, G., Menabue, L.: Inorg. Chem. 19, 125–129 (1980) CrossRefGoogle Scholar
  33. 33.
    Willett, R.D.: J. Chem. Phys. 44, 39–42 (1966) ADSCrossRefGoogle Scholar
  34. 34.
    Sun, H., Harms, K., Sundermeyer, J.: Z. Kristallogr. 220, 42–44 (2005) CrossRefGoogle Scholar
  35. 35.
    Lorenzo, S., Horn, C., Craig, D., Scudder, M., Dance, I.: Inorg. Chem. 39, 401–405 (2000) CrossRefGoogle Scholar
  36. 36.
    Bond, M.R., Willett, R.D., Rubenacker, G.V.: Inorg. Chem. 29, 2713–2720 (1990) CrossRefGoogle Scholar
  37. 37.
    Barros-Garcia, F.J., Bernalte-Garcia, A., Rolando, F.J., Giles, F.L., Galan, A.P., Zahinos, E.V.: Z. Anorg. Allg. Chem. 631, 1898–1905 (2005) CrossRefGoogle Scholar
  38. 38.
    William, E., Hatfield, E., Van Ooijen, W.E., Reedijk, J.A.C.: J. Chem. Soc. Dalton Trans., 2121–2124 (1980) Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Sondra Walha
    • 1
  • Houcine Naïli
    • 1
  • Samia Yahyaoui
    • 1
  • Basem Fares Ali
    • 2
  • Mark M. Turnbull
    • 3
  • Tahar Mhiri
    • 1
  • Seik Weng Ng
    • 4
  1. 1.Laboratoire de l’Etat Solide, Département de ChimieFaculté des Sciences de SfaxSfaxTunisie
  2. 2.Department of ChemistryAl al-Bayt UniversityMafraqJordan
  3. 3.Carlson School of Chemistry and BiochemistryClark UniversityWorcesterUSA
  4. 4.Chemistry Department, Faculty of ScienceUniversity of MalayaKuala LumpurMalaysia

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