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Crystal and molecular structure of the Fu-4,4O’-bipyridyl-bis[trans-C,O-nitrate-2-(2O’-thienyl-3-ido)pyridine-palladium] complex

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Abstract

The synthesis and determination of the crystal and molecular structure of the binuclear complex fu-4,4′-bipyridyl-bis-[trans-C,0-nitrate-2-(2′-thienyl–3-ido)pyridine-palladium] is described (C28H20N6O6Pd2S2: a = 12.3914(11) Å, b = 9.8929(7) Å, c = 12.4058(12) Å, α = 90(0)β, ß = 105.440(40)α, γ = 90(0)α, V = 1465.9(0) Å3, monoclinic symmetry, P2 1/n (14), Z = 4, d x = 1.843 g/cm3 ). The pyridine rings of 4,4′-bipyridyl are shown to be in the orthogonal position with respect to the coordination planes of palladium centers both in the solid state and solution

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Authors and Affiliations

  1. A. I. Gertsen State Pedagogical University, St. Petersburg, Russia

    A. G. Panova & K. P. Balashev

  2. Max Planck Institute, Dresden, Germany

    I. Prots

  3. St. Petersburg State University, St. Petersburg, Russia

    V. S. Fundamenskii

Authors
  1. A. G. Panova
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  2. I. Prots
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  3. V. S. Fundamenskii
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  4. K. P. Balashev
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Correspondence to A. G. Panova.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 5, pp. 965–968, September–October, 2010

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Panova, A.G., Prots, I., Fundamenskii, V.S. et al. Crystal and molecular structure of the Fu-4,4O’-bipyridyl-bis[trans-C,O-nitrate-2-(2O’-thienyl-3-ido)pyridine-palladium] complex. J Struct Chem 51, 931–934 (2010). https://doi.org/10.1007/s10947-010-0141-9

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  • DOI: https://doi.org/10.1007/s10947-010-0141-9

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