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Crystal structure of L-leucinium tetrafluoroantimonate(III)

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Abstract

The crystal structure of L-leucinium tetrafluoroantimonate(III) of the composition (C6H14NO2)SbF4 (orthorhombic symmetry: a = 6.1459(6) Å, b = 14.994(1) Å, c = 24.789(2) Å, Z = 8, P 212121 space group) synthesized for the first time is determined. The (C6H14NO2)SbF4 structure represents a new structure type of tetrafluoroantimonate(III). It is formed by (C6H14NO2)+ cations and chain complex [Sb2F8]n 2n anions composed of Sb2F8 dimers linked into chains by bridging F atoms. The Sb2F8 dimers consist of SbF3 and SbF5 groups bound by bridging fluoride atoms of the SbF5 group. Chains in the structure are linked by N-H…F, N-H…O, and O-H…F hydrogen bonds into a three-dimensional framework.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok, Russia

    A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, L. A. Zemnikhova & E. V. Kovaleva

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  1. A. A. Udovenko
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  2. N. V. Makarenko
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  3. R. L. Davidovich
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  4. L. A. Zemnikhova
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  5. E. V. Kovaleva
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Correspondence to A. A. Udovenko.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 5, pp. 940–944, September–October, 2010.

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Udovenko, A.A., Makarenko, N.V., Davidovich, R.L. et al. Crystal structure of L-leucinium tetrafluoroantimonate(III). J Struct Chem 51, 904–908 (2010). https://doi.org/10.1007/s10947-010-0137-5

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  • DOI: https://doi.org/10.1007/s10947-010-0137-5

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