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Journal of Structural Chemistry

, Volume 51, Issue 3, pp 582–584 | Cite as

Crystal and molecular structure of [RuNO(NO2)4OHCuPy n ] heterometallic complexes

  • G. A. Kostin
  • A. O. Borodin
  • N. V. Kuratieva
Article

Abstract

Heterometallic complexes [RuNO(NO2)4OHCuPy2(H2O)] (I) and [RuNO(NO2)4OHCuPy3] (II) are described structurally for the first time. In complex I, the ruthenium anion is coordinated to the copper atom by the bridging OH group and two bridging nitro groups; in complex II, by the bridging OH group and one bridging nitro group. Dimers are formed in the crystal lattice of complex II due to the interaction of the copper atom and the nitro group of the ruthenium anion in trans position to the bridging NO2 group.

Keywords

copper ruthenium heterometallic complexes nitroso complexes 

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • G. A. Kostin
    • 1
  • A. O. Borodin
    • 1
  • N. V. Kuratieva
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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