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First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O

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The structure of the interaction products of (NH4)2[Ru(NO)Cl5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl] × [Ru(NO)(NH3)Cl4]2Cl-2H2O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) Å, b = 8.202(2) Å, c = 11.844(2) Å; β= 101.54(3)°.

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References

  1. M. J. Clarke, Coord. Chem. Rev., 232, 69 (2002).

    Article  CAS  Google Scholar 

  2. E. Tfouni, M. Krieger, B. R. McGarvey, and D. W. Franco, ibid., 236, 57 (2003).

    Article  CAS  Google Scholar 

  3. A. S. Torsoni, B. F. de Barros, J. C. Toledo, et al., Nitric Oxide Biol. Chem., 6, No. 3, 247 (2002).

    Article  Google Scholar 

  4. P. G. Zanichelli, H. F. G. Estrela, R. C. Spadari-Bratfisch, et al., ibid., 16, No. 2, 189 (2007).

    Article  CAS  Google Scholar 

  5. L. A. Kusch, L. S. Plotnikova, Yu. N. Shvachko, et al., J. Phys. IV France, 114, 459 (2004).

    Article  Google Scholar 

  6. L. A. Kusch, L. S. Kurochkina, E. B. Yagubskii, et al., Eur. J. Inorg. Chem., 20, 4074 (2006).

    Article  Google Scholar 

  7. L. A. Kusch, S. Golhen, O. Cador, et al., J. Cluster Sci., 17, 303 (2007).

    Article  Google Scholar 

  8. D. Schaniel, T. Woike, L. Kusch, and E. Yagubskii, Chem. Phys., 340, Nos. 1–3, 211 (2007).

    Article  CAS  Google Scholar 

  9. O. A. Plyusnina, V. A. Emel’yanov, I. A. Baidina, et al., J. Struct. Chem., 48, No. 1, 114 (2007).

    Article  CAS  Google Scholar 

  10. M. A. Il’in, N. V. Kuratieva, O. A. Kirichenko, et al., Acta Crystallogr., E61, Part 06, i126 (2005).

  11. F. Bottomley, J. Chem. Soc. Dalton Trans., 15, 1600–1605 (1974).

    Article  Google Scholar 

  12. M. A. Il’in, V. A. Emel’yanov, I. A. Baidina, et al., Rus. J. Inorg. Chem., 52, No. 1, 62 (2007).

    Article  Google Scholar 

  13. V. A. Emel’yanov, I. A. Baidina, S. A. Gromilov, et al., J. Struct. Chem., 41, No. 6, 1030 (2000).

    Article  Google Scholar 

  14. A. S. Salomov, N.v A. Parpiev, Kh. T. Sharipov, et al., Zh. Neorg. Khim., 29, No. 10, 2608 (1984).

    CAS  Google Scholar 

  15. V. A. Emel’yanov, I. A. Baidina, M. A. Il’in, and S. A. Gromilov J. Struct. Chem., 47, No. 2, 380 (2006).

    Article  Google Scholar 

  16. M. A. Il’in, V. A. Emel’yanov, and I. A. Baidina, ibid., 49, No. 6, 1090 (2008).

    Article  Google Scholar 

  17. T. A. Balakaeva, A. S. Antsyshkina, M. G. Ezernitskaya, et al., Zh. Neorg. Khim., 46, No. 5, 751 (2001).

    CAS  Google Scholar 

  18. V. A. Emel’yanov, A. V. Virovets, and I. A. Baidina, J. Struct. Chem., 49, No. 3, 566 (2008).

    Article  Google Scholar 

  19. M. A. Il’in, V. A. Emel’yanov, A. V. Belyaev, et al., Rus. J. Inorg. Chem., 53, No. 7, 1070 (2008).

    Article  Google Scholar 

  20. V. A. Emel’yanov, S. P. Khranenko, and A. V. Belyaev, ibid., 46, No. 3, 346 (2001).

    Google Scholar 

  21. G. M. Sheldrick, SHELX-97, Release 97-1, Univ. Göttingen, Germany (1997).

    Google Scholar 

  22. E. E. Mercer, W. M. Campbell, and R. M. Wallace, Inorg. Chem., 3, No. 7, 1018 (1964).

    Article  CAS  Google Scholar 

  23. E. E. Mercer and A. B. Cox, Inorg. Chim. Acta, 6, No. 4, 577 (1972).

    Article  CAS  Google Scholar 

  24. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, Inc., New York (1997).

    Google Scholar 

  25. A. A. Svetlov, N. M. Sinitsyn, and V. V. Kravchenko, Zh. Neorg. Khim., 34, No. 4, 953 (1989).

    CAS  Google Scholar 

  26. E. E. Mercer, W. A. McAlister, and J. R. Durig, Inorg. Chem., 5, No. 11, 1881 (1966).

    Article  CAS  Google Scholar 

  27. V. A. Emel’yanov, A. V. Virovets, I. A. Baidina, et al., Inorg. Chem. Comm., 4, No. 1, 33 (2001).

    Article  Google Scholar 

  28. C. W. B. Bezerra, S. C. D. Silva, M. T. P. Gambardella, et al., Inorg. Chem., 38, No. 25, 5660 (1999).

    Article  CAS  Google Scholar 

  29. V. A. Emel’yanov, I. A. Baidina, S. A. Gromilov, et al., J. Struct. Chem., 41, No. 6, 1030 (2000).

    Article  Google Scholar 

  30. S. I. Gorelsky, S. C. Silva, A. B. P. Lever, and D. W. Franco, Inorg. Chim. Acta, 300–302, 698 (2000).

    Article  Google Scholar 

  31. V. A. Emel’yanov, I. A. Baidina, S. A. Gromilov, et al., J. Struct. Chem., 43, No. 2, 304 (2002).

    Article  Google Scholar 

  32. V. A. Emel’yanov, I. A. Baidina, S. P. Khranenko, et al., ibid., 44, No. 1, 37 (2003).

    Article  Google Scholar 

  33. N. N. Nevskii, N.M. Sinitsyn, and A.A. Svetlov, Zh. Neorg. Khim., 35, No. 5, 1159 (1990).

    CAS  Google Scholar 

  34. T. S. Khodashova, M. A. Porai-Koshits, V. S. Sergienko, et al., J. Struct. Chem., 13, No. 6, 1024 (1972).

    Article  Google Scholar 

  35. V. A. Emel’yanov, I. A. Baidina, S. A. Gromilov, et al., ibid., 41, No. 3, 463 (2000).

    Article  Google Scholar 

  36. V. A. Emel’yanov, A. V. Belyaev, M. A. Fedotov, et al., Proc. of the 12th Nikolaev Conf. [in Russian], Novosibirsk (2001), p. 35.

  37. V. A. Emel’yanov, A. V. Belyaev, M. A. Fedotov, and S. P. Khranenko, Proc. of the 17th Internet. Chernyaev Conf. on Chemistry, Analytics, and Technology of Platinum Metals [in Russian], Moscow (2001), p. 49.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Il’in, V. A. Emel’yanov & I. A. Baidina

  2. Novosibirsk State University, Novosibirsk, Russia

    M. A. Il’in & V. A. Emel’yanov

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  1. M. A. Il’in
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  2. V. A. Emel’yanov
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  3. I. A. Baidina
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Correspondence to M. A. Il’in.

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Original Russian Text Copyright © 2010 by M. A. Il’in, V. A. Emel’yanov, and I. A. Baidina

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 1, pp. 105–112, January–February, 2010.

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Il’in, M.A., Emel’yanov, V.A. & Baidina, I.A. First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O. J Struct Chem 51, 99–106 (2010). https://doi.org/10.1007/s10947-010-0014-2

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  • DOI: https://doi.org/10.1007/s10947-010-0014-2

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