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Journal of Structural Chemistry

, Volume 51, Issue 1, pp 99–106 | Cite as

First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O

  • M. A. Il’in
  • V. A. Emel’yanov
  • I. A. Baidina
Article

The structure of the interaction products of (NH4)2[Ru(NO)Cl5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl] × [Ru(NO)(NH3)Cl4]2Cl-2H2O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) Å, b = 8.202(2) Å, c = 11.844(2) Å; β= 101.54(3)°.

Keywords

ruthenium nitroso complexes ammine complexes chloro complexes single crystal X-ray diffraction analysis IR spectroscopy 

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • M. A. Il’in
    • 1
    • 2
  • V. A. Emel’yanov
    • 1
    • 2
  • I. A. Baidina
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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