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Journal of Structural Chemistry

, Volume 50, Supplement 1, pp 143–151 | Cite as

Theoretical study of the conformational features of triosmium clusters

  • V. A. Potemkin
  • N. N. Ivshina
  • V. A. Maksakov
Article

Abstract

The article summarizes the results of the study of conformational states of triosmium clusters with organic ligands. Special attention is paid to the structural features of molecular carbonyl cluster complexes with M n (CO) m L organic ligands. The effect of the structure surface charge, solvent, cluster crystalline state, and intermolecular and intramolecular interactions on the cluster conformational state is also determined.

Keywords

conformational analysis cluster complexes osmium 

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • V. A. Potemkin
    • 1
  • N. N. Ivshina
    • 1
    • 3
  • V. A. Maksakov
    • 2
  1. 1.Chelyabinsk State UniversityChelyabinskRussia
  2. 2.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia
  3. 3.I. Ya. Postovskii Institute of Organic Synthesis, Ural DivisionRussian Academy of SciencesEkaterinburgRussia

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