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Journal of Structural Chemistry

, Volume 50, Issue 5, pp 926–929 | Cite as

Molecular and crystal structure of 2,4-diethoxycarbonyl-5-hydroxy-5-methyl-3-phenyl-N-(3-chlorophenyl)-1-cyclohexenylamine

  • A. P. Kriven’ko
  • É. A. Grigor’eva
  • A. V. Grigor’ev
  • V. V. Sorokin
  • S. F. Solodovnikov
Article

Abstract

Arylamination of 2,4-diethoxycarbonyl-5-hydroxy-5-methyl-3-phenylcyclohexanone affords 2,4-diethoxycarbonyl-5-hydroxy-5-methyl-3-phenyl-N-(3-chlorophenyl)-1-cyclohexenylamine. A distorted semi-chair conformation with psedoequatorial orientation of all substituents except the pseudoaxial OH-group is established based on the spectral and single crystal XRD data. The presence of an intramolecular N-H...O=C hydrogen bond is noted.

Keywords

X-ray structural analysis enaminoesters cyclohexenes 

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • A. P. Kriven’ko
    • 1
  • É. A. Grigor’eva
    • 1
  • A. V. Grigor’ev
    • 2
  • V. V. Sorokin
    • 1
  • S. F. Solodovnikov
    • 3
  1. 1.Saratov State UniversitySaratovRussia
  2. 2.NITA-FARM Co. LtdSaratovRussia
  3. 3.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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