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Journal of Structural Chemistry

, Volume 49, Issue 2, pp 193–196 | Cite as

Method for evaluating the probability of structural isomer-isomer transformations with large numbers of quasidegenerations of the energy levels of the interactant subsystems

  • L. A. Gribov
Article

Abstract

It is shown how the theory developed by the author and regarding the structural transformations of molecules as the result of the resonance mixing between the vibronic wave functions of the corresponding states of subsystems can be extended to the case with an arbitrary number of the resonant and quasiresonant energy levels.

Keywords

structural transformations nonradiative transitions quasiresonant energy levels 

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References

  1. 1.
    L. A. Gribov and V. I. Baranov, Theory and Methods for Calculating the Molecular Processes: Spectra, Chemical Transformations, and Molecular Logics [in Russian], KomKniga, Moscow (2006).Google Scholar
  2. 2.
    R. Feynman, R. Leyton, and M. Sands, Feynman Physics Lectures [Russian translation], Vol. 8, Quantum Mechanics, Mir, Moscow (1966).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2008

Authors and Affiliations

  1. 1.V. I. Vernadskii Institute of Geochemistry and Analytical ChemistryRussian Academy of SciencesMoscowRussia

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