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Method for evaluating the probability of structural isomer-isomer transformations with large numbers of quasidegenerations of the energy levels of the interactant subsystems

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Abstract

It is shown how the theory developed by the author and regarding the structural transformations of molecules as the result of the resonance mixing between the vibronic wave functions of the corresponding states of subsystems can be extended to the case with an arbitrary number of the resonant and quasiresonant energy levels.

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References

  1. L. A. Gribov and V. I. Baranov, Theory and Methods for Calculating the Molecular Processes: Spectra, Chemical Transformations, and Molecular Logics [in Russian], KomKniga, Moscow (2006).

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  2. R. Feynman, R. Leyton, and M. Sands, Feynman Physics Lectures [Russian translation], Vol. 8, Quantum Mechanics, Mir, Moscow (1966).

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Authors and Affiliations

  1. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, Russia

    L. A. Gribov

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  1. L. A. Gribov
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Correspondence to L. A. Gribov.

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Original Russian Text Copyright © 2008 by L. A. Gribov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 2, pp. 207–210, March–April, 2008.

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Gribov, L.A. Method for evaluating the probability of structural isomer-isomer transformations with large numbers of quasidegenerations of the energy levels of the interactant subsystems. J Struct Chem 49, 193–196 (2008). https://doi.org/10.1007/s10947-008-0113-5

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  • DOI: https://doi.org/10.1007/s10947-008-0113-5

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