Journal of Structural Chemistry

, Volume 49, Issue 4, pp 753–757 | Cite as

Crystal structure of Tl5{[Nb2S4Br8]Br}

  • A. L. Gushchin
  • M. N. Sokolov
  • E. V. Peresypkina
  • V. P. Fedin
Brief Communications


By the high-temperature reaction of Nb2S4Br4 and TlBr a thallium salt of the anionic cluster complex [Nb2S4Br8]4− is obtained. Its crystal structure is determined by X-ray structural analysis. The complex is also characterized by Raman spectroscopy and electrospray-mass-spectrometry.

Key words

cluster thallium niobium crystal structure 


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Copyright information

© Pleiades Publishing, Ltd. 2008

Authors and Affiliations

  • A. L. Gushchin
    • 1
  • M. N. Sokolov
    • 1
  • E. V. Peresypkina
    • 1
  • V. P. Fedin
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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