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Journal of Structural Chemistry

, Volume 49, Issue 4, pp 696–700 | Cite as

Crystal structures of cesium and rubidium chlorites

  • A. I. Smolentsev
  • D. Yu. Naumov
Article

Abstract

Rubidium and cesium chlorites are prepared and studied by single crystal and powder X-ray diffraction. The compounds are isostructural; crystallize in the orthorhombic system; space group Cmcm, Z = 4. Unit cell parameters: a = 6.3464(8) Å, b = 6.4223(8) Å, c = 7.7493(9) Å for RbClO2 and a = 6.5998(9) Å, b = 6.6116(9) Å, c = 8.3161(11) Å for CsClO2. The structures can be represented as 3D frameworks formed by metal cations and chlorite anions acting as tetradentate bridging and bidentate chelating oxygen ligands.

Keywords

crystal structure chlorites rubidium cesium 

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References

  1. 1.
    R. Curti, V. Riganti, and S. Locchi, Acta Crystallogr., B10, No. 11, 687–691 (1957).CrossRefGoogle Scholar
  2. 2.
    J. Cooper and R. E. Marsh, ibid., B14, No. 2, 202/203 (1961).Google Scholar
  3. 3.
    M. Okuda, M. Ishihara, M. Yamanaka, et al., ibid., C46, No. 10, 1755–1759 (1990).Google Scholar
  4. 4.
    R. B. Gillespie, R. A. Sparks, and K. N. Trueblood, ibid., B12, No. 11, 867–872 (1959).CrossRefGoogle Scholar
  5. 5.
    C. Tarimci, R. D. Rosenstein, and E. Schempp, ibid., B32, No. 2, 610–612 (1976).Google Scholar
  6. 6.
    V. Tazolli, V. Riganti, G. Giuseppetti, and A. Coda, ibid., B31, No. 4, 1032–1037 (1975).Google Scholar
  7. 7.
    C. Tarimci and E. Schempp, ibid., B31, No. 8, 2146–2149 (1975).Google Scholar
  8. 8.
    T. Pakkanen, ibid., B35, No. 11, 2670–2672 (1979).Google Scholar
  9. 9.
    R. E. Marsh, ibid., C47, No. 8, 1775 (1991).Google Scholar
  10. 10.
    A. Coda, G. Giuseppetti, and C. Tadini, Periodico di Mineralogia, 34, 27–47 (1965).Google Scholar
  11. 11.
    C. Castellani Bisi, Acta Crystallogr., C40, No. 7, 1120/1121 (1984).Google Scholar
  12. 12.
    A. I. Smolentsev and D. Yu. Naumov, ibid., C61, No. 2, i17–i19 (2005).Google Scholar
  13. 13.
    A. I. Smolentsev and D. Yu. Naumov, ibid., E61, No. 11, i246–i248.Google Scholar
  14. 14.
    A. I. Smolentsev and D. Yu. Naumov, ibid, i294/i250.Google Scholar
  15. 15.
    A. I. Smolentsev and D. Yu. Naumov, ibid., C61, No. 5, i49/i50.Google Scholar
  16. 16.
    Bruker AXS Inc. (2004). APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11) and SHELXTL (Version 6.12). Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA.Google Scholar
  17. 17.
    M. I. Naumova, N. V. Kuratieva, D. Yu. Naumov, and N. V. Podberezskaya, J. Struct. Chem., 45, No. 1, 107–113 (2004).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2008

Authors and Affiliations

  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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