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Journal of Structural Chemistry

, Volume 49, Issue 1, pp 160–164 | Cite as

New crystal modification of the di(nitrato)di(aqua)palladium(II) complex β-trans-[Pd(NO3)2(H2O)2]

  • S. A. Gromilov
  • S. P. Khranenko
  • I. A. Baidina
  • A. V. Virovets
  • E. V. Peresypkina
Article

Abstract

Single crystals of a new modification of the di(nitrato)di(aqua)palladium(II) complex β-trans-[Pd(NO3)2(H2O)2] were obtained. Their crystal structure was determined: monoclinic crystal system, a = 5.7469(4) Å, b = 5.3942(6) Å, c = 10.0956(10) Å, β = 97.401(3)°, P21/c, Z = 2, d calc = 2.851 g/cm3, Bruker X8 APEX CCD, MoK α , 836 independent reflections, room temperature. The square-plane coordination of the Pd atom is formed by four oxygen atoms (Pd-O(NO3) 2.003(3) Å and Pd-O(H2O) 2.021(4) Å) and completed to a distorted bipyramid by two intramolecular contacts (Pd…O(NO3) 2.893 Å). A comparative crystal-chemical analysis with α-trans-[Pd(NO3)2(H2O)2] was carried out.

Keywords

palladium nitrates coordination compounds crystal structure crystal chemistry 

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References

  1. 1.
    B. M. Gatehause, S. E. Livingstone, and R. S. Nyholm, J. Chem. Soc., No. 10, 4222 (1957).Google Scholar
  2. 2.
    C. C. Addison and B. G. Ward, Chem. Commun., No. 6, 155 (1966).Google Scholar
  3. 3.
    V. S. Shmidt, N. A. Shorokhov, A. A. Vashman, et al., Zh. Neorg. Khim., 27, No. 5, 1254 (1982).Google Scholar
  4. 4.
    Y. Laligant, G. Ferey, and A. Le Bail, Mat. Res. Bull., 26, 269–275 (1991).CrossRefGoogle Scholar
  5. 5.
    S. P. Khranenko, I. A. Baidina, S. A. Gromilov, and A. V. Belyaev, J. Struct. Chem., 41, No. 4, 709–712 (2000).CrossRefGoogle Scholar
  6. 6.
    S. P. Khranenko, I. A. Baidina, S. A. Gromilov, and A. V. Belyaev, ibid., 46, No. 6, 1060–1065 (2005).CrossRefGoogle Scholar
  7. 7.
    S. P. Khranenko, I. A. Baidina, and S. A. Gromilov, ibid., 48, No. 6, 1152–1155 (2007).CrossRefGoogle Scholar
  8. 8.
    G. M. Sheldrick, SHELXS-97 and SHELXL. Program for the Refinement of Crystal Structure, Univ. Göttingen, Germany (1997).Google Scholar
  9. 9.
    S. V. Borisov, J. Struct. Chem., 27, No. 3, 486–488 (1986).CrossRefGoogle Scholar
  10. 10.
    S. A. Gromilov and S. V. Borisov, ibid., 44, No. 4, 664–680 (2003).CrossRefGoogle Scholar
  11. 11.
    V. A. Blatov, IUCr Cryst. Comm. Newslett., issue 7, 4–38 (http://www.iucr.org/iucr-top/comm/ccom/newsletters/) (2006).

Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • S. A. Gromilov
    • 1
  • S. P. Khranenko
    • 1
  • I. A. Baidina
    • 1
  • A. V. Virovets
    • 1
  • E. V. Peresypkina
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk

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