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Journal of Structural Chemistry

, Volume 48, Issue 6, pp 1118–1123 | Cite as

Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]·6H2O and Cs4[Re6Se8(OH)6]·8H2O

  • K. A. Brylev
  • Yu. V. Mironov
  • S.-J. Kim
  • V. E. Fedorov
Article

Abstract

The salts Cs4[Re6S8(OH)6]·6H2O (1) and Cs4[Re6Se8(OH)6]·8H2O (2) were obtained by the reactions of Re6S8Br2 and Re6Se8Br2 with a CsOH melt with further solution of the products in water and crystallization of 1 and 2 from the aqueous solutions. The structure of the compounds was established by X-ray single crystal diffraction analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 14.175(2) Å, b = 11.321(2) Å, c = 17.503(2) Å, V = 2808.5(7) Å3, Z = 4, d calc = 5.003 g/cm3; compound 2 crystallizes in the triclinic space group \(P\bar 1\) with unit cell parameters a = 9.020(4) Å, b = 9.127(4) Å, c = 10.289(4) Å, α = 79.589(7)°, β = 75.829(7)°, γ = 72.186(7)°, V = 776.8(6) Å3, Z = 1, d calc = 5.402 g/cm3.

Keywords

octahedral cluster rhenium synthesis crystal structure hydrate 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • K. A. Brylev
    • 1
    • 2
  • Yu. V. Mironov
    • 1
  • S.-J. Kim
    • 2
  • V. E. Fedorov
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk
  2. 2.EWHA Women’s UniversitySeoulKorean Republic

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