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Physicochemical study of rhodium sulfite

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Abstract

Diamagnetic rhodium sulfite Na15(NH4)3[Rh4(μ-SO3)6(SO3)7(H2O)5]·10H2O was synthesized. An X-ray photoelectron spectroscopy study and chemical analysis revealed that rhodium in this compound was in the oxidation state 2+. The thermal and chemical properties of the compound were investigated. Based on XRPA, IR, and EPR spectroscopy and analytical data about the chemical properties, a hypothesis about the structure of the complex has been formulated.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    A. V. Belyaev & P. E. Plyusnin

  2. “V. N. Gulidov Nonferrous Metals Plant” OAO, Krasnoyarsk

    V. D. Il’yashevich

Authors
  1. A. V. Belyaev
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  2. V. D. Il’yashevich
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  3. P. E. Plyusnin
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Correspondence to A. V. Belyaev.

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Original Russian Text Copyright © 2007 by A. V. Belyaev, V. D. Il’yashevich, and P. E. Plyusnin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 6, pp. 1113–1119, November–December, 2007.

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Belyaev, A.V., Il’yashevich, V.D. & Plyusnin, P.E. Physicochemical study of rhodium sulfite. J Struct Chem 48, 1046–1052 (2007). https://doi.org/10.1007/s10947-007-0169-7

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  • DOI: https://doi.org/10.1007/s10947-007-0169-7

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