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Journal of Structural Chemistry

, Volume 48, Issue 6, pp 1046–1052 | Cite as

Physicochemical study of rhodium sulfite

  • A. V. Belyaev
  • V. D. Il’yashevich
  • P. E. Plyusnin
Article

Abstract

Diamagnetic rhodium sulfite Na15(NH4)3[Rh4(μ-SO3)6(SO3)7(H2O)5]·10H2O was synthesized. An X-ray photoelectron spectroscopy study and chemical analysis revealed that rhodium in this compound was in the oxidation state 2+. The thermal and chemical properties of the compound were investigated. Based on XRPA, IR, and EPR spectroscopy and analytical data about the chemical properties, a hypothesis about the structure of the complex has been formulated.

Keywords

complex rhodium sulfite ion synthesis XPS IR spectroscopy TGA magnetic properties structure 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • A. V. Belyaev
    • 1
  • V. D. Il’yashevich
    • 2
  • P. E. Plyusnin
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk
  2. 2.“V. N. Gulidov Nonferrous Metals Plant” OAOKrasnoyarsk

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