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Journal of Structural Chemistry

, Volume 48, Issue 4, pp 673–679 | Cite as

Thermal behavior of n-alcohols, benzene, and toluene in water urea and water ethyleneglycol systems

  • V. P. Korolev
Article

Abstract

Relations are suggested for calculating the heat characteristics of alcohols, benzene, and toluene in aqueous solutions of urea and ethylene glycol. The solution heat of an alcohol shows greater dependence on the glycol concentration, while the heat capacity of solution, on the urea concentration. For n-butanol in aqueous glycol, the characteristic temperature at which the solution heat of the alcohol is zero decreases as the glycol concentration increases. The dependence of the characteristic temperature of 1-butanol on the urea concentration has a maximum.

Keywords

aqueous solutions nonelectrolytes thermal behavior alcohols benzene toluene 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  1. 1.Institute of Solution ChemistryRussian Academy of SciencesIvanovo

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