Journal of Structural Chemistry

, Volume 48, Issue 1, pp 122–127 | Cite as

Synthesis and crystal structure of copper(II) bis-chelate comprising a nitrile derivative of 3-imidazoline nitroxide

  • A. B. Burdukov
  • N. V. Pervukhina
  • G. I. Roschupkina
  • V. A. Reznikov


Syntheses of a nitroxide radical 2-(1-oxyl-2,2,5,5-tetramethyl-imidazolin-4-yliden)-3-oxo-5-phenylpentannitrile \((HL^{CH_2 CH_2 Ph} )\) and its copper(II) complex are reported. The coordination compound is characterized by the single crystal X-ray diffraction analysis (a = 11.647(2) Å, b = 13.269(3) Å, c = 13.844(3) Å, α = 61.83(2)°, β = 88.13(2)°, γ = 74.12(2)°, space group \(P\bar 1\)). The \(Cu(L^{CH_2 CH_2 Ph} )_2 (H_2 O)\) complex has a molecular structure.


nitroxide radicals complexes synthesis crystal structure 


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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • A. B. Burdukov
    • 1
  • N. V. Pervukhina
    • 1
  • G. I. Roschupkina
    • 2
  • V. A. Reznikov
    • 2
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk
  2. 2.N. N. Vorozhtsov Institute of Organic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk

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