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Metal solid solutions obtained by thermolysis of Pt and Re salts. Crystal structure of [Pt(NH3)4](ReO4)2

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Abstract

A complex salt of tetraammineplatinum(II) perrhenate [Pt(NH3)4](ReO4)2 has been synthesized. Crystal data: a = 5.1847(6) Å, b = 7.7397(8) Å, c = 7.9540(9) Å, α = 69.531(3)°, β = 79.656(3)°, γ = 77.649(3)°, V = 290,19(6) Å3, space group \(P\bar 1\), Z = 1, d x = 4.370 g/cm3. The products of decomposition of [Pt(NH3)4](ReO4)2 in a hydrogen atmosphere were investigated using X-ray phase analysis. In definite temperature modes, these are Pt0.33Re0.67 solid solutions based on Re with hcp cell parameters a = 2.76 Å, c = 4.42 Å. The products of thermolysis obtained from other precursor complex salts containing both Pt and Re were investigated. Thus Pt0.75Re0.25 solid solution with a = 3.905(3) Å was obtained from (NH4)2[ReCl6]0.25[PtCl6]0.75.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Russia

    I. V. Korolkov, A. V. Zadesenets, S. A. Gromilov, K. V. Yusenko, I. A. Baidina & S. V. Korenev

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  1. I. V. Korolkov
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  2. A. V. Zadesenets
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  3. S. A. Gromilov
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  4. K. V. Yusenko
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  5. I. A. Baidina
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  6. S. V. Korenev
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Original Russian Text Copyright © 2006 by I. V. Korolkov, A. V. Zadesenets, S. A. Gromilov, K. V. Yusenko, I. A. Baidina, and S. V. Korenev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 3, pp. 503–511, May–June, 2006.

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Korolkov, I.V., Zadesenets, A.V., Gromilov, S.A. et al. Metal solid solutions obtained by thermolysis of Pt and Re salts. Crystal structure of [Pt(NH3)4](ReO4)2 . J Struct Chem 47, 489–498 (2006). https://doi.org/10.1007/s10947-006-0327-3

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  • DOI: https://doi.org/10.1007/s10947-006-0327-3

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