Advertisement

Journal of Structural Chemistry

, Volume 47, Issue 1, pp 102–105 | Cite as

Molecular and crystal structure of 2-benzylidene-6-furfurylidene-cyclohexanone

  • A. G. Golikov
  • A. P. Kriven’ko
  • A. A. Bugaev
  • S. F. Solodovnikov
Article

Abstract

Single crystal X-ray diffraction has been used to find out that 2-benzyliden-6-furfurylidene-cyclohexanone has the E,E-configuration and s-cis-conformation of the furfurylidene fragment. The furfurylidene substituent and the carbonyl group exhibit the utmost conjugation; the conjugation in the benzylidene fragment is not perfect.

Keywords

2-benzylidene-6-furfurylidene-cyclohexanone bis-α,β-enones structural X-ray diffraction study 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Z. Jia, J. W. Quail, V. K. Arora, and J. R. Dimmock, Acta Crystallogr., C45, 285–289 (1989).Google Scholar
  2. 2.
    D. N. Dhar, The Chemistry of Chalcones and Related Compounds, Wiley, New York, (1981), 285 p.Google Scholar
  3. 3.
    S. P. Panda and S. G. Kulkarni, Combust. Flame, 28, 25–27 (1977).CrossRefGoogle Scholar
  4. 4.
    J. Kawamata, K. Ihoue, and T. Inabe, Bull. Chem. Soc. Jpn., 71, 2777–2786 (1998).CrossRefGoogle Scholar
  5. 5.
    A. P. Kriven’ko, A. A. Bugaev, and A. G. Golikov, Khim. Geterotzikl. Soedin., No. 2, 191–195 (2005).Google Scholar
  6. 6.
    L. J. Bellamy, The Infrared Spectra of Complex Molecules, [Russian translation] Methuen and Co, Ltd., London (1954).Google Scholar
  7. 7.
    N. T. Komyagin, A. N. Yanovskii, Yu. T. Struchkov, and A. P. Kriven’ko, Zh. Org. Khim., 27, 551–555 (1991).Google Scholar
  8. 8.
    K. Nakanishi, “Infrared absorption spectroscopy: practical”, Nankodo Company Limited-Holden-Day, Inc., Tokyo-San Francisco, 1962, 233 pp. (Russian translation).Google Scholar
  9. 9.
    G. M. Sheldrick, SHELX-97, Release 97-2, Univ. Göttingen, Germany (1997).Google Scholar
  10. 10.
    S. S. Batzanov, Zh. Neorg. Khim., 36, 3015–3037 (1991).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • A. G. Golikov
    • 1
  • A. P. Kriven’ko
    • 1
  • A. A. Bugaev
    • 1
  • S. F. Solodovnikov
    • 2
  1. 1.Cherhyshevski State UniversitySaratov
  2. 2.Nikolaev Institute of Inorganic chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk

Personalised recommendations