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Journal of Structural Chemistry

, Volume 47, Issue 1, pp 41–47 | Cite as

Statistical thermodynamics and dielectric properties of dipole-quadrupole hard-sphere fluid

  • G. B. Litinskii
Article

Abstract

Within a hindered rotation model, approximate analytical expressions have been obtained for thermodynamic functions and the Kirkwood factor of the model polar fluid of dipole-quadrupole hard spheres in the nearest neighbor approximation. A peculiarity of the considered system from the viewpoint of the hindered rotation model is the ability to generate a three-dimensional grid of quadrupole-bonded molecules, as indicated by the behavior of quadrupole hard-sphere fluid at large values of the quadrupole moment.

Keywords

statistical thermodynamics Kirkwood factor dielectric permittivity polar fluids dipolequadrupole hard spheres quadrupole hard spheres 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • G. B. Litinskii
    • 1
  1. 1.Kharkov Guard Institute of Tank Troops NTU “KhPI”Kharkov

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