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Journal of Structural Chemistry

, Volume 46, Issue 6, pp 1066–1071 | Cite as

Synthesis and structure of bis(2-phenylethyl) phosphine selenide

  • B. G. Sukhov
  • N. K. Gusarova
  • N. I. Ivanova
  • M. V. Bogdanova
  • O. N. Kazheva
  • G. G. Aleksandrov
  • O. A. D’yachenko
  • L. M. Sinegovskaya
  • S. F. Malysheva
  • B. A. Trofimov
Article

Abstract

Bis(2-phenylethyl)phosphine selenide was obtained with 86% yield from bis(2-phenylethyl)phosphine and selenium. XRD, IR, UV, and multinuclear NMR spectroscopic studies revealed that the phosphorus atom in the bis(2-phenylethyl)phosphine selenide molecule is four-coordinated irrespective of the phase state (crystals or solution).

Keywords

bis(2-phenylethyl)phosphine selenide four-coordinated phosphorus selenone tautomeric form XRD spectral techniques 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • B. G. Sukhov
    • 1
  • N. K. Gusarova
    • 1
  • N. I. Ivanova
    • 1
  • M. V. Bogdanova
    • 1
  • O. N. Kazheva
    • 2
  • G. G. Aleksandrov
    • 3
  • O. A. D’yachenko
    • 2
  • L. M. Sinegovskaya
    • 1
  • S. F. Malysheva
    • 1
  • B. A. Trofimov
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian DivisionRussian Academy of SciencesIrkutsk
  2. 2.Institute of Chemical Physics ProblemsRussian Academy of SciencesChernogolovka
  3. 3.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscow

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