Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of supramolecular compounds of cucurbituryl with the chalcocyanide cluster complex [Re4Te4(CN)12]4− and a manganese(II) aqua complex

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Supramolecular compounds [Mn(H2O)4(C36H36N24O12)]2[Re4Te4(CN)12]·12.5H2O (1), (H3O)2[{Mn(H2O)4 (C36H36N24O12)}{Mn(H2O)4} 2{Re4Te4(CN)12}2]·3.5H2O (2) and [{Mn(H2O)3Cl} 2(C36H36N24O12)]Cl2·6H2O (3) were obtained by crystallization at room temperature from water solutions containing macrocyclic cavitand cucurbituryl (C36H36N24O12), aqua complex of manganese(II) (1–3) and chalcocyanide cluster complex [Re4Te4(CN)12]4− (1, 2). From XRD analysis, the cucurbituryl molecule is bound with one (1, 2) or two atoms of manganese (3) through oxygen atoms of carbonyl groups. Compound 2 has a chain structure where cluster complexes of rhenium are linked through bridge manganese atoms into a polymeric ribbon. Compounds 1 and 3 have the island-like type of structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. G. Samsonenko, O. A. Geras’ko, and V. P. Fedin, Usp. Khim., No. 9, 841–860 (2002).

  2. Y. M. Jeon, J. Kim, D. Whang, and K. Kim, J. Am. Chem. Soc., 118, 9790/9791 (1996).

    Article  CAS  Google Scholar 

  3. D. Whang, J. Heo, J. H. Park, and K. Kim, Angew. Chem. Int. Ed., 37, 78–80 (1998).

    Article  CAS  Google Scholar 

  4. J. Heo, S.-Y. Kim, D. Whang, and K. Kim, ibid., 38, 641–643 (1999).

    Article  CAS  Google Scholar 

  5. J. Heo, J. Kim, D. Whang, and K. Kim, Inorg. Chim. Acta., 297, 307–312 (2000).

    Article  CAS  Google Scholar 

  6. W. A. Freeman, W. L. Mock, and N.-Y. Shih, J. Am. Chem. Soc., 103, 7367/7368 (1981).

    Article  CAS  Google Scholar 

  7. W. A. Freeman, Acta Crystallogr., B40, 382–387 (1984).

    CAS  Google Scholar 

  8. D. G. Samsonenko, A. A. Sharapova, M. N. Sokolov, et al., Koordinats. Khim., 27, No. 1, 12–17 (2001).

    Google Scholar 

  9. O. A. Geras’ko, A. V. Viriovets, D. G. Samsonenko, et al., Izv. Ross. Akad. Nauk, Ser. Khim., No. 3, 562–569 (2003).

  10. D. G. Samsonenko, J. Lipkowski, O. A. Gerasko, et al., Eur. J. Inorg. Chem., No. 9, 2380–2388 (2002).

  11. D. G. Samsonenko, O. A. Geras’ko, Ya. Lipkovski, et al., Izv. Ross. Akad. Nauk, Ser. Khim., No. 10, 1763–1765 (2002).

  12. D. G. Samsonenko, M. N. Sokolov, O. A. Geras’ko, A. V. Virovets, et al., ibid., 2020–2027 (2003).

  13. D. G. Samsonenko, M. N. Sokolov, A. V. Virovets, et al., Eur. J. Inorg. Chem., No. 1, 167–172 (2001).

  14. D. G. Samsonenko, O. A. Geras’ko, T. V. Mit’kina, et al., Koordinats. Khim., 29, No. 3, 178–186 (2003).

    Google Scholar 

  15. P. Cintas, J. Inclus. Phenom., 17, 205–220 (1994).

    Article  CAS  Google Scholar 

  16. W. L. Mock, in: Comprehensive Supramolecular Chemistry., V. 2., F. Vögtle (ed.), Pergamon, Oxford (1996), pp. 477–493.

    Google Scholar 

  17. Yu. V. Mironov, A. V. Virovets, S. B. Artemkina, and V. Ye. Feforov, Zh. Strukt. Khim., 40, No. 2, 374–379 (1999).

    Google Scholar 

  18. Yu. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Inorg. Chem., 36, 944–946 (1997).

    Article  CAS  Google Scholar 

  19. G. M. Sheldrick, XPREP Version 5.04., Siemens Analytical X-ray Instruments Inc., Madison (1995).

    Google Scholar 

  20. G. M. Sheldrick, SADABS, Absorption Corrections for Area Detector Data, Univ. Göttingen, Germany (1997).

    Google Scholar 

  21. G. M. Sheldrick, SHELX-97. Release 97-2., Univ. Göttingen, Germany (1998).

    Google Scholar 

  22. Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, et al., Eur. J. Inorg. Chem., No. 14, 2591–2595 (2003).

  23. Yu. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Z. Kristallogr., 212, 308 (1997).

    CAS  Google Scholar 

  24. Yu. V. Mironov and V. E. Fedorov, Izv. Ross. Akad. Nauk, Ser. Khim., No. 4, 529–539 (2002).

  25. Yu. V. Mironov, A. V. Virovets, W. S. Sheldrick, and V. E. Fedorov, Polyhedron., 20, 969–974 (2001).

    Article  CAS  Google Scholar 

  26. F. H. Allen, Acta Crystallogr., B58, 380–388 (2002).

    CAS  Google Scholar 

  27. D. G. Samsonenko, Synthesis and Structure of Supramolecular Compounds of Cucurbituryl with Mono-and Polynuclear Aqua Complexes of Metals [in Russian], Candidate of Chemistry Dissertation, Institute of Inorganic Chemistry, Novosibirsk (2002).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    D. G. Samsonenko, Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, O. A. Gerasko, V. P. Fedin & V. E. Fedorov

  2. Institute of Analytical Chemistry, University of Ruhr, Bohum, Germany

    W. S. Sheldrick

Authors
  1. D. G. Samsonenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. V. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Efremova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. Yu. Naumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. A. Gerasko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. P. Fedin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. E. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. W. S. Sheldrick
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text Copyright © 2005 by D. G. Samsonenko, Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, O. A. Gerasko, V. P. Fedin, V. E. Fedorov, and W. S. Sheldrick

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 46, Supplement, pp. S119–S126, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Samsonenko, D.G., Mironov, Y.V., Efremova, O.A. et al. Synthesis and crystal structure of supramolecular compounds of cucurbituryl with the chalcocyanide cluster complex [Re4Te4(CN)12]4− and a manganese(II) aqua complex. J Struct Chem 46 (Suppl 1), S121–S129 (2005). https://doi.org/10.1007/s10947-006-0162-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-006-0162-6

Keywords

Search

Navigation