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Journal of Structural Chemistry

, Volume 46, Supplement 1, pp S121–S129 | Cite as

Synthesis and crystal structure of supramolecular compounds of cucurbituryl with the chalcocyanide cluster complex [Re4Te4(CN)12]4− and a manganese(II) aqua complex

  • D. G. Samsonenko
  • Yu. V. Mironov
  • O. A. Efremova
  • D. Yu. Naumov
  • O. A. Gerasko
  • V. P. Fedin
  • V. E. Fedorov
  • W. S. Sheldrick
Article

Abstract

Supramolecular compounds [Mn(H2O)4(C36H36N24O12)]2[Re4Te4(CN)12]·12.5H2O (1), (H3O)2[{Mn(H2O)4 (C36H36N24O12)}{Mn(H2O)4} 2{Re4Te4(CN)12}2]·3.5H2O (2) and [{Mn(H2O)3Cl} 2(C36H36N24O12)]Cl2·6H2O (3) were obtained by crystallization at room temperature from water solutions containing macrocyclic cavitand cucurbituryl (C36H36N24O12), aqua complex of manganese(II) (1–3) and chalcocyanide cluster complex [Re4Te4(CN)12]4− (1, 2). From XRD analysis, the cucurbituryl molecule is bound with one (1, 2) or two atoms of manganese (3) through oxygen atoms of carbonyl groups. Compound 2 has a chain structure where cluster complexes of rhenium are linked through bridge manganese atoms into a polymeric ribbon. Compounds 1 and 3 have the island-like type of structure.

Keywords

rhenium manganese cluster cucurbituryl crystal structure 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • D. G. Samsonenko
    • 1
  • Yu. V. Mironov
    • 1
  • O. A. Efremova
    • 1
  • D. Yu. Naumov
    • 1
  • O. A. Gerasko
    • 1
  • V. P. Fedin
    • 1
  • V. E. Fedorov
    • 1
  • W. S. Sheldrick
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk
  2. 2.Institute of Analytical ChemistryUniversity of RuhrBohumGermany

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