Journal of Structural Chemistry

, Volume 46, Issue 2, pp 328–333 | Cite as

Crystal structure and thermal investigation of bis-(1-thenoyl-4,4,4-trifluorobutan-1,3-dionato) lead(II)

  • I. A. Baidina
  • P. A. Stabnikov
  • S. A. Gromilov
  • I. K. Igumenov


Lead(II) complex with thenoyltrifluoroacetone has been prepared and characterized by IR spectroscopy, powder and single crystal X-ray diffraction. Crystal data for PbO4S2F6C16H8: a = 20.457(4) Å, b = 11.292(2) Å, c = 8.409(2) Å; β = 91.37(3)°, space group C2/c, Z = 4, d calc = 2.222 g/cm3. The molecule of the complex is non-planar, average distances Pb-O are 2.384 Å, chelate angle O-Pb-O is 75.0°. The structure is of polymeric chain nature, Pb...Pb separation in the chains being 4.311 Å. The complex Pb(ttf)2 is stable under heating up to 250°C. The compound is less volatile than Cu(ttf)2 or Fe(ttf)3.


lead (II) β-diketonates X-ray diffraction analysis crystal chemistry 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    V. V. Krisyuk, I. A. Baidina, S. A. Gromilov, and E. V. Bolshakova, Zh. Strukt. Khim., 35, No. 6, 197–201 (1994).Google Scholar
  2. 2.
    V. V. Krisyuk, I. A. Baidina, S. A. Gromilov, et al., ibid., 38, No. 3, 526–531 (1997).Google Scholar
  3. 3.
    V. V. Krisyuk, “Synthesis and Physical Chemical Investigation of Lead(II) β-diketonates, ” Chemical Sciences Candidate’s Dissertation, Novosibirsk (1996).Google Scholar
  4. 4.
    I. K. Igumenov, Yu. V. Chumachenko, and S. V. Zemskov, Problems of Chemistry and Application of Metal Diketonates [in Russian], Nauka, Moscow (1982).Google Scholar
  5. 5.
    C. A. Hunter and J. K. M. Sanders, J. Am. Chem. Soc., 112, 5525–5534 (1990).CrossRefGoogle Scholar
  6. 6.
    J. A. Pretorius and J. C. A. Boeyns, J. S. Afr. Chem. Inst., 30, 153–157 (1977).Google Scholar
  7. 7.
    C. Lecomte, D. Bayeul, N. Senglet, and R. Guilard, Polyhedron, 7, 303–306 (1988).CrossRefGoogle Scholar
  8. 8.
    Yu. Yunpeng, Xu. Zheng, You. Xiaozeng, et al., Chin. J. Inorg. Chem., 4, 30–35 (1988).Google Scholar
  9. 9.
    Dong-Mei Wang, Rui-Na Yang, Yi-Min Hu, and Dou-Man Jin, Chin. J. Struct. Chem., 15, No. 4, 327–329 (1996).Google Scholar
  10. 10.
    C. E. Urdy, Cryst. Struct. Commun., 5, 527–531 (1976).Google Scholar
  11. 11.
    H. Soling, Acta Chem. Scand. Ser. A, 30, 163–170 (1976).CrossRefGoogle Scholar
  12. 12.
    S. Aynetchi, P. B. Hitchcock, E. A. Sendon, et al., Inorg. Chem. Acta, 113, No. 1, L7–L9 (1986).CrossRefGoogle Scholar
  13. 13.
    V. V. Krisyuk, V. B. Durasov, and I. K. Igumenov, Sib. Khim. Zh., No. 4, 82–86 (1991).Google Scholar
  14. 14.
    G. M. Sheldrick, SHELX-97. Release 97-1, Univ. Göttingen, Germany (1997).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • I. A. Baidina
    • 1
  • P. A. Stabnikov
    • 1
  • S. A. Gromilov
    • 1
  • I. K. Igumenov
    • 1
  1. 1.Nikolaev Institute of Inorganic ChemistryRussian Academy of Sciences, Siberian DivisionNovosibirsk

Personalised recommendations