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Journal of Structural Chemistry

, Volume 46, Issue 1, pp 109–115 | Cite as

Synthesis, crystal structure, and properties of [Rh(NH3)5Cl][ReBr6]

  • K. V. Yusenko
  • S. A. Gromilov
  • I. A. Baidina
  • I. V. Korolkov
  • S. V. Korenev
Article

Abstract

A binary complex salt [Rh(NH3)5Cl][ReBr6] has been synthesized and investigated by X-ray diffraction analysis. Crystal data: a = 8.541(5) Å, b = 12.015(6) Å, c = 16.496(9) Å; α = 73.695(10)°, β = 89.746(9)°, γ = 89.676(9)°, V = 1624.7 Å3, space group \(P\overline 1 \), Z = 4, D x = 3.635 g/cm3, R = 0.12. It is shown that the product of thermolysis of the salt in the atmosphere of hydrogen and helium is a solid solution Rh0.5Re0.5 with hcp cell parameters a = 2.731(5) Å and c = 4.368(7) Å.

Keywords

rhenium rhodium X-ray diffraction analysis metals solid solution 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • K. V. Yusenko
    • 1
  • S. A. Gromilov
    • 1
  • I. A. Baidina
    • 1
  • I. V. Korolkov
    • 1
  • S. V. Korenev
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirsk

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