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Theoretical study of the conformational states of triosmium clusters with a chiral pinane ligand

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Abstract

A theoretical study of the conformational state of triosmium clusters with a chiral pinane ligand (μ-H)Os3(CO)10(μ-ONC10H14) has been performed. The potential curves of internal rotation of organic ligands around the N-C bond in cluster complexes in the crystalline state and in various solvents with continual consideration for the parameters of the latter have been determined. The structures of conceivable conformers and isomers are considered; the factors responsible for their formation and stability are examined. The relations between the conformational and crystalline structures of the cluster and the effect of intra-and intermolecular interactions on its structure are revealed.

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Authors and Affiliations

  1. Chelyabinsk State University, Russia

    V. A. Potemkin

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    V. A. Maksakov

  3. Novosibirsk State University, Russia

    V. S. Korenev

Authors
  1. V. A. Potemkin
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  2. V. A. Maksakov
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  3. V. S. Korenev
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Original Russian Text Copyright © 2005 by V. A. Potemkin, V. A. Maksakov, and V. S. Korenev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 47–52, January–February, 2005.

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Potemkin, V.A., Maksakov, V.A. & Korenev, V.S. Theoretical study of the conformational states of triosmium clusters with a chiral pinane ligand. J Struct Chem 46, 43–48 (2005). https://doi.org/10.1007/s10947-006-0007-3

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  • DOI: https://doi.org/10.1007/s10947-006-0007-3

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