Abstract
The Cu(acac)2 complex was investigated by X-ray emission and XANES spectroscopy using synchrotron radiation. Structural data for the complex were obtained in chloroform solution and C2F matrix. The experimental spectra and their fitting on a single scale of binding energies point to possible relaxation effects. As shown by model quantum-chemical calculations, the structure and energy position of the LUMOs constructed from the vacant metal 4p, 5p AOs strongly depends on the nature of the nearest environment.
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Original Russian Text Copyright © 2004 by L. N. Mazalov, S. V. Trubina, E. S. Fomin, I. M. Oglezneva, G. K. Parygina, N. V. Bausk, and I. K. Igumenov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 844–851, September–October, 2004.
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Mazalov, L.N., Trubina, S.V., Fomin, E.S. et al. X-Ray Study of the Electronic Structure of Copper(II) Acetylacetonate. J Struct Chem 45, 800–807 (2004). https://doi.org/10.1007/s10947-005-0061-2
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DOI: https://doi.org/10.1007/s10947-005-0061-2