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Journal of Structural Chemistry

, Volume 45, Issue 3, pp 518–522 | Cite as

Crystal structure of Ba(VUO6)2

  • E. V. Alekseev
  • E. V. Suleimanov
  • E. V. Chuprunov
  • G. K. Fukin
Brief Communications

Abstract

The crystal structure of Ba(VUO6)2 was determined by X-ray diffraction at 243 K: monoclinic crystal system, space group P21/c, unit cell parameters a=6.4992(6) Å, b=8.3803(8) Å, c=10.4235(9) Å, β=104.749(2) °, Z=2. The structure contains close-packed [VUO6] 2∞ δ- layers formed by the dimers of the flattened U2O12 pentagonal bipyramids and by the dimers of V2O8 square pyramids. The neighboring layers are bound by the statistically distributed barium atoms.

Keywords

barium uranovanadate crystal structure X-ray diffraction analysis uranyl dehydration structural rearrangements 

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Copyright information

© Springer Science+Business Media, Inc. 2004

Authors and Affiliations

  • E. V. Alekseev
    • 1
  • E. V. Suleimanov
    • 1
  • E. V. Chuprunov
    • 1
  • G. K. Fukin
    • 2
  1. 1.N. I. Lobachevskii Nizhnii Novgorod State UniversityRussia
  2. 2.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii Novgorod

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