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Crystal structure of Ba(VUO6)2

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Abstract

The crystal structure of Ba(VUO6)2 was determined by X-ray diffraction at 243 K: monoclinic crystal system, space group P21/c, unit cell parameters a=6.4992(6) Å, b=8.3803(8) Å, c=10.4235(9) Å, β=104.749(2) °, Z=2. The structure contains close-packed [VUO6] δ-2∞ layers formed by the dimers of the flattened U2O12 pentagonal bipyramids and by the dimers of V2O8 square pyramids. The neighboring layers are bound by the statistically distributed barium atoms.

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Authors and Affiliations

  1. N. I. Lobachevskii Nizhnii Novgorod State University, Russia

    E. V. Alekseev, E. V. Suleimanov & E. V. Chuprunov

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod

    G. K. Fukin

Authors
  1. E. V. Alekseev
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  2. E. V. Suleimanov
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  3. E. V. Chuprunov
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  4. G. K. Fukin
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Original Russian Text Copyright © 2004 by E. V. Alekseev, E. V. Suleimanov, E. V. Chuprunov, and G. K. Fukin

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 544–548, May–June 2004.

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Alekseev, E.V., Suleimanov, E.V., Chuprunov, E.V. et al. Crystal structure of Ba(VUO6)2 . J Struct Chem 45, 518–522 (2004). https://doi.org/10.1007/s10947-005-0022-9

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  • DOI: https://doi.org/10.1007/s10947-005-0022-9

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