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Cationic hydrogel and graphene oxide based cationic hydrogel with embedded palladium nanoparticles in the aerobic oxidation of olefins

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Abstract

Poly(3-acrylamidopropyl) trimethyl ammonium chloride, p(APMACl), has been synthesized from (3-acrylamidopropyl) trimethyl ammonium chloride, (APTMACl), via free radical polymerization reaction technique under mild conditions. In addition, in the presence of cationic monomer APTMACl, graphene oxide (GO) forms supramolecular stable hydrogel, p(APTMACl)/GO. P(APTMACl) and p(APTMACL)/GO have been successfully utilized for the in situ synthesis and stabilization of Pd nanoparticles within the hydrogel matrix. These hydrogel composites were characterized by Fourier transform infrared (FT-IR), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and atomic absorption spectroscopy (AA). The morphology of the p(APTMACl) reveals the formation of homogeneous and highly porous material. Catalytic activity of p(APTMACl)-Pd and p(APTMACL)/GO-Pd catalysts were investigated in the aerobic oxidation of olefins by emphasizing the effects of different parameters such as temperature, substituent effect, etc. Under similar experimental conditions, catalyst p(APTMACl)/GO-Pd resulted in higher oxidation conversion than p(APTMACl)-Pd. The catalyst was easily recovered from the reaction medium and it could be re-used for other three runs without significant loss of activity.

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Acknowledgements

Authors are thankful to University of Zanjan for financial support of this study.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, 45371-38791, Iran

    Massomeh Ghorbanloo, Nafiseh Moharramkhani, Tahereh Mokary Yazdely & Hassan Hosseini Monfared

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  1. Massomeh Ghorbanloo
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  2. Nafiseh Moharramkhani
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  3. Tahereh Mokary Yazdely
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Correspondence to Massomeh Ghorbanloo.

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Ghorbanloo, M., Moharramkhani, N., Yazdely, T.M. et al. Cationic hydrogel and graphene oxide based cationic hydrogel with embedded palladium nanoparticles in the aerobic oxidation of olefins. J Porous Mater 26, 433–441 (2019). https://doi.org/10.1007/s10934-018-0620-5

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