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Rapid and phase pure synthesis of microporous copper silicate (CuSH–1Na) with 12-ring channel system

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Abstract

Phase pure sample of the microporous copper silicate CuSH–1Na has been obtained by simplified hydrothermal method without using additives (H2O2 and Na2HPO4). Ion exchange of Na+ by Cs+, Ca2+ and Sr2+ ions showed that the structure can suffer partial replacement of the charge compensating cations. Ion exchange with Cs+ resulted in distinct dehydration while the ion exchange with Sr2+ increased the total amount of water. Water content in the Ca-exchanged sample is comparable to the as-synthesized sodium phase. Raman spectroscopy revealed that the divalent cations as Ca2+ and Sr2+ induce stronger local structural deformations than the monovalent Cs+. These structural changes have been also followed by the refined lattice distortions. Magnetic analyses showed that CuSH–1Na presents a very weak ferromagnetic interaction along the Cu2+ chains with a nearly vanishing Curie–Weiss temperature. This magnetic coupling is associated with super-super-exchange interactions through Cu–Na–O–Na–Cu paths. Antiferromagnetic coupling, attributed to inter-chains super-super-exchange interactions, competes with the ferromagnetic one and prevails at the lowest temperature.

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Acknowledgements

This work was supported by the Portuguese Foundation for Science and Technology (IF/01516/2013 and IF/00686/2014).

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Authors and Affiliations

  1. IFIMUP and IN - Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia da Faculdade de Ciências da Universidade do Porto, Rua do Campo Alegre, 687, Porto, Portugal

    Armandina M. L. Lopes

  2. Department of Chemistry, CICECO - Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal

    Zhi Lin

  3. Department of Physics, University of Minho, Guimarães, Portugal

    Stanislav Ferdov

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  1. Armandina M. L. Lopes
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  2. Zhi Lin
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  3. Stanislav Ferdov
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Lopes, A.M.L., Lin, Z. & Ferdov, S. Rapid and phase pure synthesis of microporous copper silicate (CuSH–1Na) with 12-ring channel system. J Porous Mater 25, 1309–1316 (2018). https://doi.org/10.1007/s10934-017-0541-8

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