Journal of Porous Materials

, Volume 23, Issue 6, pp 1679–1685 | Cite as

Syntheses and crystal structures of two new nickel (II) metal-organic frameworks with a polydentate ligand



Two metal-organic frameworks {Na2[Ni(L)2(H2O)]}n (1) and {[Ni(L)(H2O)]·2H2O}n (2) (H2L = N-pyrazinesulfonyl-glycine) have been prepared by reaction of the same proportion Ni(CH3COO)2·4H2O and H2L but with different pH values in water-ethanol mixed solution, and were characterized by X-ray diffraction, elemental analysis, IR spectrum. X-ray analysis indicates that 1 is a 3-D polymeric structure containing two different secondary building units (SBUs, NiN4O2 and Na2O8), in which two deprotonated L ligands coordinate in a facial tridentate arrangement about the NiII atom. While complex 2 is a 1-D chain structure, in which three N atoms of two L ligands coordinate to one NiII atom but its pyrazyl N atom monodentate-bridge to adjacent NiII atom. Thus SBUs Ni(L)(H2O)2 are obtained between two neighboring NiII atoms and they connect one another to form this new polymer. In the crystal, two different hydrogen bond motifs and π···π stacking are found in 1 and 2.


Synthesis N-pyrazinesulfonyl-glycine Nickel complex Coordination polymer Crystal structure 



This work was supported by the Guangxi Provincial Department of Education (Nos. KY2015ZD130, YB2014414) and the Natural Science Foundation of Guangxi Province (Nos. 2014GXNSFAA118035, 2014GXNSFBA118040). The supports of the National Natural Science Foundation of China (No. 51402158) is gratefully acknowledged. The authors also acknowledge the financial supported by the Opening Project of Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization (No. 2015KLOG09).


  1. 1.
    C.Y. Lee, O.K. Farha, B.J. Hong, A.A. Sarjeant, S.T. Nguyen, J.T. Hupp, J. Am. Chem. Soc. 133, 15858 (2011)CrossRefGoogle Scholar
  2. 2.
    A.J. Graham, A.M. Banu, T. Düren, A. Greenaway, S.C. McKellar, J.P.S. Mowat, K. Ward, P.A. Wright, S.A. Moggach, J. Am. Chem. Soc. 136, 8606 (2014)CrossRefGoogle Scholar
  3. 3.
    T.C. Wang, W. Bury, D.A. Gómez-Gualdrón, N.A. Vermeulen, J.E. Mondloch, P. Deria, K. Zhang, P.Z. Moghadam, A.A. Sarjeant, R.Q. Snurr, J.F. Stoddart, J.T. Hupp, O.K. Farha, J. Am. Chem. Soc. 137, 3585 (2015)CrossRefGoogle Scholar
  4. 4.
    Z.L. Wu, J. Dong, W.Y. Ni, B.W. Zhang, J.Z. Cui, B. Zhao, Inorg. Chem. 54, 5266 (2015)CrossRefGoogle Scholar
  5. 5.
    Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 54, 4862 (2015)CrossRefGoogle Scholar
  6. 6.
    H. Wang, F.Y. Yi, S. Dang, W.G. Tian, Z.M. Sun, Cryst. Growth Des. 14, 147 (2014)CrossRefGoogle Scholar
  7. 7.
    L. Li, J. Zhang, L. Ma, Z. Zhang, S. Wang, S. Li, G. Zhou, J. Coord. Chem. 66, 638 (2013)CrossRefGoogle Scholar
  8. 8.
    Y. Wen, T. Sheng, Z. Xue, Y. Wang, C. Zhuo, X. Zhu, S. Hu, X. Wu, Inorg. Chem. 54, 3951 (2015)CrossRefGoogle Scholar
  9. 9.
    Z. Chen, Y. Su, W. Xiong, L. Wang, F. Liang, M. Shao, CrystEngComm 11, 318 (2009)CrossRefGoogle Scholar
  10. 10.
    L.F. Ma, L.Y. Wang, X.K. Huo, Y.Y. Wang, Y.T. Fan, J.G. Wang, S.H. Chen, Cryst. Growth Des. 8, 620 (2008)CrossRefGoogle Scholar
  11. 11.
    Y. Shen, N. Ma, L. Wu, H. Song, Inorg. Chim. Acta 429, 51 (2015)CrossRefGoogle Scholar
  12. 12.
    Q. Feng, M. Yan, L. Wu, H. Song, H. Yu, Inorg. Chem. Commun. 43, 1 (2014)CrossRefGoogle Scholar
  13. 13.
    S. Li, W. Zhang, Y. Zhu, Q. Zhao, F. Huo, Cryst. Growth Des. 15, 1017 (2015)CrossRefGoogle Scholar
  14. 14.
    Y. Liu, H. Li, Y. Han, X. Lv, H. Hou, Y. Fan, Cryst. Growth Des. 12, 3505 (2012)CrossRefGoogle Scholar
  15. 15.
    D. Sarma, S. Natarajan, Cryst. Growth Des. 11, 5415 (2011)CrossRefGoogle Scholar
  16. 16.
    J.M. Li, Z.F. Shi, K.H. He, Chin. J. Struct. Chem. 1, 135 (2016)Google Scholar
  17. 17.
    J.M. Li, Bull. Korean Chem. Soc. 4, 1177 (2014)CrossRefGoogle Scholar
  18. 18.
    S.W. Wright, K.N. Hallstrom, J. Org. Chem. 71, 1080 (2006)CrossRefGoogle Scholar
  19. 19.
    L.F. Ma, L.Y. Wang, J.G. Wang, Y.F. Wang, X. Feng, Inorg. Chem. Acta 7, 2241 (2006)CrossRefGoogle Scholar
  20. 20.
    G.M. Sheldrick, SHELXL-97. Program for X-ray Crystal Structure Refinement (Göttingen University, Göttingen, 1997)Google Scholar
  21. 21.
    A.K. Boudalis, J.M. Clemente-Juan, F. Dahan, J.P. Tuchagues, Inorg. Chem. 43, 1574 (2004)CrossRefGoogle Scholar
  22. 22.
    J. Bernstein, R.E. Davis, L. Shimoni, N.L. Chang, Angew. Chem. Int. Ed. 34, 1555 (1995)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas Resource Effective Utilization, College of Petroleum and Chemical EngineeringQinzhou UniversityQinzhouPeople’s Republic of China
  2. 2.Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), School of Chemistry and PharmacyGuangxi Normal UniversityGuilinPeople’s Republic of China

Personalised recommendations