Journal of Porous Materials

, Volume 23, Issue 4, pp 1059–1064 | Cite as

Preparation and adsorption performance of palm fiber-based nanoporous carbon materials with high specific surface area

  • Siyu Li
  • Yan Wang
  • Yuan Wei
  • Jing Zeng
  • Wenying Shi
  • Yanwei Wang


Palm fiber-based nanoporous carbon materials with high specific surface area had been successfully prepared from palm fiber by zinc chloride activated method. Structures of the obtained materials were studied by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and a surface area and pore size analysis method. Adsorption performance of the as-prepared materials was evaluated by a batch method on 722S spectrophotometer. Results indicated that the obtained materials had abundant pore structure, e.g. the Brunauer–Emmett–Teller (BET) surface area and total pore volume could be up to 3892 m2/g and 2.901 m3/g, respectively. BET surface area increased first, and then decreased with increasing the activator ratio, while the mesopores proportion increased significantly. Adsorption experiments showed that the obtained material had good adsorption performance. The adsorption equilibrium between dye and palm fiber-based activated carbon (PFAC) achieved within 2 min at the experiment conditions. The adsorption capacity of PFAC-3 increased with increasing the initial dye concentration.


Palm fiber Nanoporous carbon Adsorption Specific surface area 



This research was supported by the project of NNSFC (51403052), Science and Technology Project of Henan Province (142102210402) and Science and Technology Project of Zhengzhou (121PPTGG357-2).

Supplementary material

10934_2016_163_MOESM1_ESM.doc (9.2 mb)
Supplementary material 1 (DOC 9439 kb)


  1. 1.
    N. Daneshvar, M. Ayazloo, A.R. Khataee et al., Biological decolorization of dye solution containing malachite green by microalgae Cosmarium sp. Bioresour. Technol. 98, 1176–1182 (2007)CrossRefGoogle Scholar
  2. 2.
    M.R. Khan, S.I. Mozumder, A. Islam et al., Methylene blue adsorption onto water hyacinth: batch and column study. Water Air Soil Pollut. 223, 2943–2953 (2012)CrossRefGoogle Scholar
  3. 3.
    P.S. Kumar, S. Ramalingam, K. Sathishkumar, Removal of methylene blue dye from aqueous solution by activated carbon prepared from cashew nut shell as a new low-cost adsorbent. Korean J. Chem. Eng. 28, 149–155 (2011)CrossRefGoogle Scholar
  4. 4.
    J.F. de Brito, L. de Oliveira Ferreira, M.C.R. Pereira et al., Adsorption of aromatic compounds under magnetic field influence. Water Air Soil Pollut. 223, 3545–3551 (2012)CrossRefGoogle Scholar
  5. 5.
    L. Wang, Q. Li, A.Q. Wang, Adsorption of cationic dye on N,O-carboxymethyl-chitosan from aqueous solutions: equilibrium, kinetics, and adsorption mechanism. Polym. Bull. 65, 961–975 (2010)CrossRefGoogle Scholar
  6. 6.
    M. Asgher, Biosorption of reactive dyes: a review. Water Air Soil Pollut. 223, 2417–2435 (2012)CrossRefGoogle Scholar
  7. 7.
    S.T. Akar, A.S. Özcan, T. Akar et al., Biosorption of a reactive textile dye from aqueous solutions utilizing an agro-waste. Desalination 249, 757–761 (2009)CrossRefGoogle Scholar
  8. 8.
    S. Srivastava, R. Sinha, D. Roy, Review: toxicological efects of malachite green. Aquat. Toxicol. 66, 319–329 (2004)CrossRefGoogle Scholar
  9. 9.
    O. Hamdaoui, M. Chiha, Removal of methylene blue from aqueous solutions by wheat bran. Acta Chim. Slov. 54, 407–418 (2007)Google Scholar
  10. 10.
    M.S. Chiou, G.S. Chuang, Competitive adsorption of dye metanil yellow and RB15 in acid solutions on chemically cross-linked chitosan beads. Chemosphere 62, 731–740 (2006)CrossRefGoogle Scholar
  11. 11.
    J. Panswed, S. Wongchaisuwan, Mechanism of dye wastewater color removal by magnesium carbonate-hydrated basic. Water Sci. Technol. 18, 139–144 (1986)Google Scholar
  12. 12.
    G. Ciardelli, L. Corsi, M. Marucci, Membrane separation for wastewater reuse in the textile industry. Resour. Conserv. Recycl. 31, 189–197 (2000)CrossRefGoogle Scholar
  13. 13.
    M.K. Purkait, A. Maiti, S. DasGupta et al., Removal of congo red using activated carbon and its regeneration. J. Hazard. Mater. 145, 287–295 (2007)CrossRefGoogle Scholar
  14. 14.
    A. Alinsafi, M. Khemis, M.N. Pons et al., Electro-coagulation of reactive textile dyes and textile wastewater. Chem. Eng. Process. 44, 461–470 (2005)CrossRefGoogle Scholar
  15. 15.
    M. Muthukumar, N. Selvakumar, Studies on the effect of inorganic salts on decolouration of acid dye effluents by ozonation. Dyes Pigments 62, 221–228 (2004)CrossRefGoogle Scholar
  16. 16.
    S. Mondal, H. Ouni, M. Dhahbi et al., Kinetic modeling for dye removal using polyelectrolyte enhanced ultrafiltration. J. Hazard. Mater. 229–230, 381–389 (2012)CrossRefGoogle Scholar
  17. 17.
    G. Gehlot, S. Verma, S. Sharma et al., Adsorption isotherm studies in the removal of malachite green dye from aqueous solution by using coal fly ash. Int. J. Chem. Stud. 3, 42–44 (2015)Google Scholar
  18. 18.
    V. Meshko, L. Markovska, M. Mincheva et al., Adsorption of basic dyes on granular activated carbon and natural zeolite. Water Res. 35, 3357–3366 (2001)CrossRefGoogle Scholar
  19. 19.
    S.Y. Li, Y.W. Wang, R.W. Fu, Preparation and weak acid dark blue adsorption studies of melamine formaldehyde-based nanoporous carbon. Proc. Inst. Mech. Eng. Part N: J. Nanoeng. Nanosyst. 227, 185–189 (2013)CrossRefGoogle Scholar
  20. 20.
    R.L. Tseng, F.C. Wu, R.S. Juang, Liquid-phase adsorption of dyes and phenols using pinewood-based activated carbons. Carbon 41, 487–495 (2003)CrossRefGoogle Scholar
  21. 21.
    P.K. Malik, Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of acid yellow 36. Dyes Pigments 56, 239–249 (2003)CrossRefGoogle Scholar
  22. 22.
    C. Namasivayam, D. Kavitha, Removal of congo red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigments 54, 47–58 (2002)CrossRefGoogle Scholar
  23. 23.
    Y. Yamashita, K. Ouchi, Influence of alkali on the carbonization process-II: carbonization of various coals and asphalt with NaOH. Carbon 20, 47–53 (1982)CrossRefGoogle Scholar
  24. 24.
    L.S. Liu, Z.Y. Liu, Z.G. Huang et al., Preparation of activated carbon honeycomb monolith directly from coal. Carbon 44, 1598–1601 (2006)CrossRefGoogle Scholar
  25. 25.
    A. Ahmadpour, D.D. Do, The preparation of active carbons fromcoal by chemical and physical activation. Carbon 34, 471–479 (1996)CrossRefGoogle Scholar
  26. 26.
    E. Daguerre, A. Guillot, F. Stoeckli, Activated carbons prepared from thermally and chemically treated petroleum and coal tar pitches. Carbon 39, 1279–1285 (2001)CrossRefGoogle Scholar
  27. 27.
    T. Tomko, R. Rajagopalan, M. Lanagan et al., High energy density capacitor using coal tar pitch derived nanoporous carbon/MnO2 electrodes in aqueous electrolytes. J. Power Sources 196, 2380–2386 (2011)CrossRefGoogle Scholar
  28. 28.
    S.Y. Li, Y.R. Liang, D.C. Wu et al., Fabrication of bimodal mesoporous carbons from petroleum pitch by a one-step nanocasting method. Carbon 48, 839–843 (2010)CrossRefGoogle Scholar
  29. 29.
    A. Demirbas, Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review. J. Hazard. Mater. 167, 1–9 (2009)CrossRefGoogle Scholar
  30. 30.
    J.M. Dias, M.C.M. Alvim-Ferraz, M.F. Almeida et al., Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review. J. Environ. Manag. 85(4), 833–846 (2007)CrossRefGoogle Scholar
  31. 31.
    B. Hu, K. Wang, L.H. Wu et al., Engineering carbon materials from the hydrothermal carbonization process of biomass. Adv. Mater. 22, 813–828 (2010)CrossRefGoogle Scholar
  32. 32.
    M. Valix, W.H. Cheung, G. McKay, Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere 56, 493–501 (2004)CrossRefGoogle Scholar
  33. 33.
    N.K. Amin, Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination 223, 152–161 (2008)CrossRefGoogle Scholar
  34. 34.
    Y. Chen, S.R. Zhai, N. Liu et al., Dye removal of activated carbons prepared from NaOH-pretreated rice husks by low-temperature solution-processed carbonization and H3PO4 activation. Bioresour. Technol. 144, 401–409 (2013)CrossRefGoogle Scholar
  35. 35.
    R.L. Liu, Y. Liu, X.Y. Zhou et al., Biomass-derived highly porous functional carbon fabricated by using a free-standing template for efficient removal of methylene blue. Bioresour. Technol. 154, 138–147 (2014)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Siyu Li
    • 1
  • Yan Wang
    • 1
  • Yuan Wei
    • 1
  • Jing Zeng
    • 1
  • Wenying Shi
    • 1
  • Yanwei Wang
    • 1
  1. 1.School of Material and Chemical EngineeringHenan Institute of EngineeringZhengzhouChina

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