Abstract
In order to prepare a highly active catalyst for the catalytic cracking of larger molecules, a novel micro-mesoporous silicoaluminophosphate composite (define as mesoporous SAPO-5) with hierarchical tri-modal pore size distributions has been firstly synthesized via post-synthetic method in acidic condition and subsequently characterized. Morphology control of the composite is attempted by adjusting pH value of the synthetic system. Three different morphologies of composite, including sphere-, rod- and net-like, are obtained in the different conditions. Possible mechanism for the formation of mesoporous SAPO-5 has been proposed. The mesoporous SAPO-5 exhibits higher cracking activity than conventional microporous SAPO-5 for cracking of 1, 3, 5-triisopropylbenzene (1, 3, 5-TIPB) under the same reaction conditions. The result indicates that the mesoporous SAPO-5 with hierarchical pore structure is favorable for catalytic cracking of large molecule. When the cumene as the reaction molecule, the microporous SAPO-5 catalyst exhibits higher conversion in catalytic cracking of cumene compared to the mesoporous SAPO-5, and the result may be attributed to that microporous SAPO-5 has much stronger acidity and specific selectivity than mesoporous SAPO-5 catalyst in catalytic cracking of cumene. Meanwhile, corresponding carbenium ion mechanism can account for the products formed during the whole reaction process.
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Acknowledgments
This work was supported by the 973 Program under Grant (No. 2003CB615802), the Foundation for State Key Laboratory of Multiphase Complex Systems (No. MPCS-2014-A-04 Y425016124 J. Q.), National Natural Science Foundation of China (No.51302266 Q. J.) and Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (Q. J.).
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Jian Qi and Quan Jin have contributed equally to this work.
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Qi, J., Jin, Q., Zhao, K. et al. Catalytic cracking of 1, 3, 5-triisopropylbenzene over silicoaluminophosphate with hierarchical pore structure. J Porous Mater 22, 1021–1032 (2015). https://doi.org/10.1007/s10934-015-9976-y
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DOI: https://doi.org/10.1007/s10934-015-9976-y