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Journal of Porous Materials

, Volume 21, Issue 3, pp 355–363 | Cite as

Template synthesis, structure, sorption properties and acidity of micro-mesoporous materials obtained from sol-precursor of zeolite BEA

  • Nataliya Shcherban
  • Roman Barakov
  • Pavel Yaremov
  • Vladimir Solomakha
  • Svitlana Gryn
  • Olena Khaynakova
  • Vladimir Ilyin
Article

Abstract

Partially zeolitized micro-mesoporous materials (the total specific surface area S BET  = 460–645 m2/g, mesopore volume V meso  = 0.30–0.57 cm3/g, mesopore diameter D meso  ≈ 5.6 nm, micropore volume V micro  = 0.11–0.16 cm3/g, micropore diameter D micro  ≈ 0.72 nm) and X-ray amorphous micro-mesoporous materials with uniform mesoporous structure (mesopore specific surface area S meso  = 820–890 m2/g, total pore volume V t  = 0.71–0.86 cm3/g, V meso  = 0.53–0.67 cm3/g, D meso  = 1.8–2.4 nm) were obtained by micellar templating of sol-precursor containing primary products of crystallization of zeolite BEA under conditions typical for forming of mesoporous molecular sieve MCM-41 (hydrothermal treatment at 100–130 °C for 3–5 days). It was found that the obtained X-ray amorphous micro-mesoporous materials contain secondary building units of zeolite BEA (five-membered rings of Si–O tetrahedra of BEA) and show acidic properties comparable to zeolite BEA.

Keywords

Micro-mesoporous materials Sol-precursor of BEA Sorption properties Acidity Template synthesis 

Notes

Acknowledgments

The microscopic study was carried out at the University of Oviedo (Oviedo, Spain), thanks to the support of the International Research Staff Exchange Scheme (IRSES) (Project 319013).

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Nataliya Shcherban
    • 1
  • Roman Barakov
    • 1
  • Pavel Yaremov
    • 1
  • Vladimir Solomakha
    • 1
  • Svitlana Gryn
    • 1
    • 2
  • Olena Khaynakova
    • 3
  • Vladimir Ilyin
    • 1
  1. 1.L.V. Pisarzhevsky Institute of Physical ChemistryNational Academy of Sciences of UkraineKievUkraine
  2. 2.Institute of High TechnologiesTaras Shevchenko Kyiv National UniversityKievUkraine
  3. 3.Chemical DepartmentUniversity of OviedoOviedoSpain

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