Skip to main content
SpringerLink
Log in

Preparation and characterization of the continuous titanium-doped ZrO2 mesoporous fibers with large surface area

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

The continuous titanium-doped ZrO2 mesoporous fibers with a large surface area (190 m2 g−1, TZ50-400) have been prepared by the sol–gel method coupled with the chemical template route. In the formation process, the self-induced acid environment of ZrOCl2·8H2O in ethanol solution was utilized to avoid a rapid hydrolysis process and the viscous sol precursors were successfully obtained for spinning fibers. X-ray photoelectron spectroscopy and UV–vis diffuse reflectance spectra were used to study the chemical environment of surface Ti(IV) and Zr((IV)) ions. The findings disclose that the partial Ti atoms (less than 30 %) enter into the ZrO2 lattice and occupy the positions of Zr atoms, while the excess Ti atoms construct the linear Ti–O–Ti chains inside the extra framework, being favorable to prevent the collapse of meso structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. K.R. Sridhar, J.A. Blanchard, Sens. Actuators B 59, 60 (1999)

    Article  CAS  Google Scholar 

  2. A.D. Brailsford, M. Yussouff, E.M. Logothetis, Sens. Actuators B 44, 321 (1997)

    Article  CAS  Google Scholar 

  3. A.O. Isenberg, Solid State Ionics 3–4, 431 (1981)

    Article  Google Scholar 

  4. A. Mineshinge, M. Inaba, Z. Ogumi, T. Takahashi, T. Kawagoe, A. Tasaka, K. Kikuchi, Solid State Ionics 86–88, 1251 (1996)

    Article  Google Scholar 

  5. H.R. Chen, J.L. Shi, W.H. Zhang, M.L. Ruan, D.S. Yan, Chem. Mater. 13, 1035 (2001)

    Article  CAS  Google Scholar 

  6. M.E. Zorn, D.T. Tompkins, W.A. Zeltner, M.A. Anderson, Appl. Catal. B 23, 1 (1999)

    Article  CAS  Google Scholar 

  7. J.H. Schattka, D.G. Shchukin, J. Jia, M. Antonietti, R.A. Caruso, Chem. Mater. 14, 5103 (2002)

    Article  CAS  Google Scholar 

  8. Q. Yuan, Y. Liu, L.L. Li, Z.X. Li, C.J. Fang, W.T. Duan, X.H. Li, C.H. Yan, Micropor. Mesopor. Mater. 124, 169 (2009)

    Article  CAS  Google Scholar 

  9. W. Zhou, K. Liu, H. Fu, K. Pan, L. Zhang, L. Wang, C. Sun, Nanotechnology 19, 035610 (2008)

    Article  Google Scholar 

  10. J.A. Knowles, M.J. Hudson, J. Chem. Soc. Chem. Commun. 20, 2083 (1995)

    Article  Google Scholar 

  11. P. Yang, D. Zhao, D.I. Margolese, B.F. Chmelka, G.D. Stucky, Nature 396, 152 (1998)

    Article  CAS  Google Scholar 

  12. X.M. Liu, G.Q. Lu, Z.F. Yan, J. Phys. Chem. B 108, 15523 (2004)

    Article  CAS  Google Scholar 

  13. E.L. Crepaldi, G.J.A.A. Soler-Illia, D. Grosso, P.A. Albouy, C. Sanchez, Chem. Commun. 15, 1582 (2001)

    Article  Google Scholar 

  14. E.L. Crepaldi, G.J.A.A. Soler-Illia, A. Bouchara, D. Grosso, D. Durand, C. Sanchez, Angew. Chem. Int. Ed. 42, 347 (2003)

    Article  CAS  Google Scholar 

  15. A.S. Deshpande, M. Niederberger, Micropor. Mesopor. Mater. 101, 413 (2007)

    Article  CAS  Google Scholar 

  16. L. Xu, H.K. Lee, Anal. Chem. 79, 5241 (2007)

    Article  CAS  Google Scholar 

  17. L. Liu, X. Tan, S. Liu, J. Am. Ceram. Soc. 89, 1156 (2006)

    Article  CAS  Google Scholar 

  18. D.H. Deng, R. Tang, X.P. Liao, B. Shi, Langmuir 24, 368 (2008)

    Article  CAS  Google Scholar 

  19. S.H. Zhan, D.R. Chen, X.L. Jiao, C.H. Tao, J. Phys. Chem. B 110, 11199 (2006)

    Article  CAS  Google Scholar 

  20. P.J. Bruinsma, A.Y. Kim, J. Liu, S. Baskaran, Chem. Mater. 9, 2507 (1997)

    Article  CAS  Google Scholar 

  21. P. Yang, D. Zhao, B.F. Chmelka, G.D. Stucky, Chem. Mater. 10, 2033 (1998)

    Article  CAS  Google Scholar 

  22. K.T. Jung, Y.H. Chu, S. Haam, Y.G. Shul, J. Non-Cryst, Solids 298, 193 (2002)

    CAS  Google Scholar 

  23. S. Madhugiri, W. Zhou, J.P. Ferraris, K.J. Balkus Jr, Micropor. Mesopor. Mater. 63, 75 (2003)

    Article  CAS  Google Scholar 

  24. M. Macias, A. Chacko, J.P. Ferraris, K.J. Balkus Jr, Micropor. Mesopor. Mater. 86, 1 (2005)

    Article  CAS  Google Scholar 

  25. S. Madhugiri, B. Sun, P.G. Smirniotis, J.P. Ferraris, K.J. Balkus Jr, Micropor. Mesopor. Mater. 69, 77 (2004)

    Article  CAS  Google Scholar 

  26. J.Y. Chen, H.C. Chen, J.N. Lin, C.S. Kuo, Mater. Chem. Phys. 107, 480 (2008)

    Article  CAS  Google Scholar 

  27. C.J. Brinker, Y.F. Lu, A. Sellinger, H.Y. Fan, Adv. Mater. 11, 579 (1999)

    Article  CAS  Google Scholar 

  28. G. Yu, L. Zhu, X. Wang, H. Che, G. Zhang, Z. Sun, H. Fan, X. Liu, D. Xu, Micropor. Mesopor. Mater. 119, 230 (2009)

    Article  CAS  Google Scholar 

  29. G. Yu, L. Zhu, X. Wang, J. Liu, D. Xu, Micropor. Mesopor. Mater. 130, 189 (2010)

    Article  CAS  Google Scholar 

  30. L. Zhu, X. Wang, G. Zhang, Q. Ren, D. Xu, Appl. Catal. B 103, 428 (2011)

    Article  CAS  Google Scholar 

  31. G. Siu, M. Stokes, Y. Lui, Phys. Rev. B 59, 3173 (1999)

    Article  CAS  Google Scholar 

  32. P. Quintard, P. Barberis, A. Mirgorodsky, T. Merle-Mejean, J. Am. Ceram. Soc. 85, 1745 (2002)

    Article  CAS  Google Scholar 

  33. A. Naumenko, Iu. Gnatiuk, N. Smirnova, A. Eremenko, Thin Solid Films 520, 4541 (2012)

    Article  CAS  Google Scholar 

  34. M.F. Best, R.A. Condrate Sr, J. Mater. Sci. Lett. 4, 994 (1985)

    Article  CAS  Google Scholar 

  35. J.W. Kriesel, M.S. Sander, T.D. Tilley, Chem. Mater. 13, 3554 (2001)

    Article  CAS  Google Scholar 

  36. J. Chastain, R.C. King Jr (eds.), (Physical Electronics, Inc, Minneapolis, 1995)

  37. Z. Luan, L. Kevan, J. Phys. Chem. B 101, 2020 (1997)

    Article  CAS  Google Scholar 

  38. A. Corma, M.T. Navarro, J.P. Pariente, J. Chem. Soc. Chem. Commun. 2, 147 (1994)

    Article  Google Scholar 

  39. E.F. Lopez, V.S. Escribano, M. Panizza, M.M. Carnasciali, G.J. Busca, Mater. Chem. 11, 1891 (2001)

    Article  Google Scholar 

  40. M.S. Morey, G.D. Stucky, J. Phys. Chem. B 103, 2037 (1999)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully appreciate the financial support from Hebei Provincial Natural Science Foundation (E2013210036, E2012210015), National Natural Science Foundation(51102172), the Nature Science Foundation of Hebei Education Department (No.Y 2011112) and National key laboratory open project fund (SKL201105SIC) .

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang, 050043, People’s Republic of China

    Gang Yu, Guanglei Zhang, Guoqiang Qin, Hua Fu, Fengqiu Ji & Jinjin Zhao

  2. State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People’s Republic of China

    Luyi Zhu

Authors
  1. Gang Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Luyi Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guanglei Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guoqiang Qin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hua Fu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Fengqiu Ji
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Jinjin Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Gang Yu or Jinjin Zhao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, G., Zhu, L., Zhang, G. et al. Preparation and characterization of the continuous titanium-doped ZrO2 mesoporous fibers with large surface area. J Porous Mater 21, 105–112 (2014). https://doi.org/10.1007/s10934-013-9753-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-013-9753-8

Keywords

Search

Navigation