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Journal of Porous Materials

, Volume 20, Issue 4, pp 663–671 | Cite as

Novel porous organosilica containing amino and β-cyclodextrin groups

  • Stephanie Degoutin
  • Maryse Bacquet
Article

Abstract

The elaboration of new hybrid mesoporous silica materials containing β-cyclodextrin groups and amine functions is reported. The synthesis is based on a direct co-condensation between β-CDAPS, a hybrid precursor obtained by reaction between tosyl-β-cyclodextrin and aminopropyltrimethoxysilane previously described, and tetraethyl orthosilicate via a sol–gel pathway templated by three different surfactants: anionic (sodium dodecylsulfate), cationic (cetyltrimethylammonium bromide) or neutral (Triton X-45) ones. The chemical structure and morphology are characterized and analyzed for all the series. Finally, the templating based mechanisms are investigated by comparing these samples with series prepared without template or without cyclodextrin.

Keywords

Organosilica Porous materials β-cyclodextrin Templating mechanisms 

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Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  1. 1.Université Lille Nord de FranceLilleFrance
  2. 2.Unité des Matériaux et Transformations (UMET)CNRS-UMR 8207Villeneuve d’Ascq CedexFrance

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