Synthesis and characterization of low density and hydrophobic silica aerogels dried at ambient pressure using sodium silicate precursor
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The present paper deals with the synthesis and characterization of low density and hydrophobic silica aerogels dried at ambient pressure using low cost sodium silicate precursor. The hydrogels were prepared by sol–gel processing of sodium silicate precursor and acetic acid catalyzed water followed by vapour passing and solvent exchange with methanol. The mixture of MeOH:trimethylchlorosilane (TMCS):hexane was used for the end capping of the silanols present on the silica surface. The process was optimized by varying vapour passing time, gel ageing time, molar ratios of H2O/Na2SiO3, CH3COOH/Na2SiO3 and TMCS/Na2SiO3 and silylation period. The aerogels have been characterized by bulk density, % of volume shrinkage, porosity, Fourier transform infrared spectroscopy, thermogravimetric and differential thermal analysis and contact angle measurements. The best quality silica aerogels in terms of low density (0.073 g/cc), higher porosity (96%) and better hydrophobicity (θ = 146°) have been obtained with the molar ratio of Na2SiO3:H2O:CH3COOH:TMCS at 1:166.6:2.25:11.9.
KeywordsAerogels Hydrophobicity Contact angle Optical transmission Ambient pressure drying
The authors are grateful to the Condensed Matter Advisory Committee, Department of Science and Technology (DST), New Delhi, Government of India, for the financial support for this work through a major research project on “Aerogels” (No. SR/S2/CMP-67/2006). Dr. A. Parvathy Rao is highly thankful to the DST for the Senior Research Associateship.
- 1.L.W. Hrubesh, Chem. Ind. 17, 824 (1990)Google Scholar
- 3.J. Fricke, A. Emmerling, Struct. Bond. 77, 27 (1992)Google Scholar
- 4.C.A.M. Mulder, J.G. Van Lierop, in Aerogels, ed. by J. Fricke (Springer, Berlin, 1986), p. 68Google Scholar
- 12.J.J. Bikerman, Surface Chemistry: Theory and Applications, 2nd edn. (Academic, New York, 1958), p. 343Google Scholar
- 13.G. Reichenaver, J. Non-cryst. Solids 350, 3482 (2004)Google Scholar
- 14.A.E. Scheidegger, The Physics of Flow Through Porous Media, 3rd edn. (University of Torento Press, Torento, 1974)Google Scholar
- 15.C.J. Brinker G.W. Scherer, Sol–Gel Science (Academic, San Diego, 1990), p. 358Google Scholar
- 16.C.J. Brinker G.W. Scherer, Sol–Gel Science (Academic, San Diego, 1990), p. 105Google Scholar
- 17.A.V. Rao, M.M. Kulkarni, D.P. Amalnerkar, Tanay Seth, J. Non-Cryst. Solids 330, 190 (2003)Google Scholar
- 18.P.C. Heimenz, Principles of Colloid and Surface Chemistry (Marcel Dekkar, New York, 1977)Google Scholar
- 20.C.J. Pouchert (ed.) Aldrich Library of FTIR Spectra, vol 2 (Aldrich Chemical, Milwaukee, 1985)Google Scholar